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书名 Catalysis 第25卷 作者James J. Spivey, Louisiana State University, USA Yi-Fan Han, East China University of Science and Technology, Shanghai, China K. M. Dooley, Louisiana State University, USA Authors Jun Bao, University of Science and Technology of China, Hefei, China A. Beretta, Politecnico di Milano, Italy Natalia Bo¨hmer, hte Aktiengesellschaft, Heidelberg, Germany Mercedes Boronat, Instituto de Tecnolog?′a Qu?′mica, Valencia, Spain Uwe Burghaus, North Dakota State University, USA De Chen, Norwegian University of Science and Technology, Norway A. Donazzi, Politecnico di Milano, Italy Xuezhi Duan, East China University of Science and Technology, China P. Forzatti, Politecnico di Milano, Italy Karin Fo¨ ttinger, Vienna University of Technology, Austria Cornelia Futter, hte Aktiengesellschaft, Heidelberg, Germany G. Groppi, Politecnico di Milano, Italy Andreas Kuschel, hte Aktiengesellschaft, Heidelberg, Germany M. Maestri, Politecnico di Milano, Italy Eko Prasetyo, hte Aktiengesellschaft, Heidelberg, Germany Thomas Roussie` re, hte Aktiengesellschaft, Heidelberg, Germany Stephan A. Schunk, hte Aktiengesellschaft, Heidelberg, Germany E. Tronconi, Politecnico di Milano, Italy Noritatsu Tsubaki, University of Toyama, Japan Xinggui Zhou, East China University of Science and Technology, China 出版社皇家化学会 页数 258 ISBN: 978-1-84973-578-0 DOI: 10.1039/9781849737203 ISSN: 0140-0568 目录Gaining insight into the kinetics of partial oxidation of light hydrocarbons on Rh, through a multiscale methodology based on advanced experimental and modeling techniques 1 A. Beretta, A. Donazzi, G. Groppi, M. Maestri, E. Tronconi and P. Forzatti 1 Introduction 1 2 The severity of the CPO process 3 3 Experimental tools for the kinetic investigation of the CPO of CH4 and light hydrocarbons under isothermal conditions: reactor designs 4 4 A theoretical tool for the kinetic investigation: microkinetic scheme of CH4 CPO on Rh 13 5 Experimental tools for the kinetic investigation of CH4 CPO in short contact time adiabatic reformers 19 6 Modeling of CPO short contact time adiabatic reformers 29 7 Case studies: analysis of spatially resolved measurements in adiabatic short contact time CPO reactors 30 8 Optimization of the thermal behavior of short contact time CPO reformers 38 9 Summary and open issues 41 References 45 Cover Image provided courtesy of computational science company Accelrys (www.accelrys.com). An electron density isosurface mapped with the electrostatic potential for an organometallic molecule. This shows the charge distribution across the surface of the molecule with the red area showing the positive charge associated with the central metal atom. Research carried out using Accelrys Materials Studioss. Catalysis, 2013, 25, ix–xi | ix c The Royal Society of Chemistry 2013 Downloaded Published on 11 March 2013 on http://pubs.rsc.org | doi:10.1039/9781849737203-FP009 Theoretical tools for studying gold nanoparticles as catalysts for oxidation and hydrogenation reactions 50 Mercedes Boronat 1 Introduction 50 2 Oxidation reactions 51 3 Hydrogenation reactions 62 4 Conclusions 72 Acknowledgements 73 References 73 PdZn based catalysts: connecting electronic and geometric structure with catalytic performance 77 Karin Fo¨ttinger 1 Introduction 77 2 Preparation, structural and electronic properties 78 3 Catalytic properties in selected applications 94 4 Conclusions and outlook 112 References 113 Structural manipulation of the catalysts for ammonia decomposition 118 Xuezhi Duan, Xinggui Zhou and De Chen 1 Introduction 118 2 Ru-based catalysts 119 3 Ni-based catalysts 126 4 Fe-based catalysts 130 5 Bimetallic catalysts 134 6 Conclusions and perspectives 135 Acknowledgements 136 References 136 Applications of electron beam lithography in surface science and catalysis – model-nano-array catalysts 141 Uwe Burghaus 1 Introduction 141 2 Nano fabrication of NAC: an example 151 3 UHV sample cleaning and sample stability 152 4 Characterization of morphology and chemical composition 154 5 Physical properties 154 6 Chemical properties and applications in surface chemistry 157 x | Catalysis, 2013, 25, ix–xi Downloaded Published on 11 March 2013 on http://pubs.rsc.org | doi:10.1039/9781849737203-FP009 View Online 7 Non-catalytic applications 163 8 Summary 163 Abbreviations 164 Short glossary of related nanofabrication techniques 165 Acknowledgments 167 References 168 High throughput technology: approaches of research in homogeneous and heterogeneous catalysis 172 Stephan A. Schunk, Natalia Bo¨hmer, Cornelia Futter, Andreas Kuschel, Eko Prasetyo and Thomas Roussie`re 1 Introduction 172 2 Homogeneous catalysis 174 3 Heterogeneous catalysis 188 4 Conclusion 207 Acknowledgement 207 References 207 Core-shell catalysts and bimodal catalysts for Fischer-Tropsch synthesis 216 Jun Bao and Noritatsu Tsubaki 1 Introduction 216 2 Core-shell catalysts for direct synthesis of isoparaffins from syngas: spatial-confinement effects and shape selectivity 218 3 Bimodal catalysts for Fischer-Tropch synthesis: chemical and spatial effects 227 4 Conclusions 243 Acknowledgements 243 References 243 Catalysis (Specialist periodical report) James J Spivey_ Yi-Fan Han_ K M Dooley-Cata.jpg QQ图片20140504120726.jpg |
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