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[资源] ★★★★★★★2014书籍超级帖二三二《聚合物纳米纤维》高清英文书籍

书名Polymer Nanofibers
Building Blocks for Nanotechnology
作者Dario Pisignano
Dipartimento di Matematica e Fisica ‘‘Ennio De Giorgi’’, University of Salento
and CNR-Istituto Nanoscienze, Lecce, Italy
Email: Dario.pisignano@unisalento.it
页数441
出版社 CRC PRESS
ISBN: 978-1-84973-574-2
ISSN: 1757-7136
目录Chapter 1 Soft Matter Nanotechnologies
1.1 Nanotechnology and Nanomaterials 1
1.2 Nanotechnology Routes from Inorganic to Organic
Materials 7
1.2.1 Lithographies 9
1.3 One-dimensional Structures and Nanostructures 13
1.4 Introduction to Polymer Physics and Engineering 15
1.4.1 Glass Transition Phenomenology 17
1.4.2 Rheology and Flow Behavior 26
1.4.2.1 Linear Viscoelastic Response and
Material Functions 27
1.4.2.2 Modeling Linear Viscoelasticity. The
Maxwell Model 35
1.4.3 Polymer Solutions 39
References 43
Chapter 2 Electrospinning
2.1 Electrostatic Spinning 50
2.1.1 Droplet Formation 51
2.1.2 Jet Formation 54
2.1.3 Jet Instabilities 57
2.1.4 Solvent Evaporation 62
2.1.5 Molecular Orientation 65
2.2 Process Parameters 68
2.3 Process Engineering 71
2.3.1 Coaxial Architectures 78
RSC Nanoscience & Nanotechnology No. 29
Polymer Nanofibers: Building Blocks for Nanotechnology
By Dario Pisignano
# D. Pisignano 2013
Published by the Royal Society of Chemistry, www.rsc.org
xi
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Published on 24 May 2013 on http://pubs.rsc.org | doi:10.1039/9781849737746-FP010
2.3.2 Collector Geometries and Alignment of
Nanofibers 82
2.3.3 Use of Composite Solutions 90
2.4 Technological Issues and Process Upscaling Towards
Industrialization 94
2.4.1 Production Yield and Reproducibility 95
2.5 Process Theory and Modeling 100
2.5.1 Early Models (1970s–1999) 102
2.5.2 Reneker and Yarin Models 103
2.5.3 Electrohydrodynamic Models 107
2.5.4 More Recent Approaches (2002–2011) 113
References 119
Chapter 3 Other Fabrication Technologies for Polymer Nanofibers
3.1 Self-assembly and Polymerization Methods 132
3.1.1 Self-assembly from Marginal Solvents 133
3.1.2 Casting Methods 137
3.1.3 Other Self-assembly Examples 139
3.1.4 Polymerization Methods 142
3.2 Nanofluidics 144
3.3 Template Synthesis 148
3.3.1 Hard Templates 149
3.3.2 Soft Templates 157
3.4 Interfacial Polymerization 168
3.5 Direct Writing Methods 172
3.6 Phase Separation 174
References 176
Chapter 4 Structural and Surface Properties of Polymer Nanofibers and
Their Applications
4.1 Structural and Mechanical Properties 189
4.1.1 Carbon Nanofibers 195
4.2 Porosity and Wettability Properties 197
4.2.1 Porosity 197
4.2.1.1 Porosity of Nanofibers Assemblies 197
4.2.1.2 Internal Porosity of Single Nanofibers 201
4.2.1.3 Surface Porosity of Single Nanofibers 201
4.2.2 Wettability 202
4.3 Applications 209
4.3.1 Filtration, Catalysis and Energy Storage 209
4.3.2 Micro- and Nanofluidics, Thermal
Management and Sensing 218
xii Contents
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4.3.3 Textiles 224
References 228
Chapter 5 Optical Properties of Polymer Nanofibers and Their
Applications
5.1 Organic Light-emitting Materials 236
5.1.1 Excitations and Electronic Transitions 237
5.1.2 Energy Transfer Mechanisms 241
5.1.3 Stimulated Emission and Lasing from Organics 247
5.2 Light-emitting Nanofibers 249
5.2.1 Molecular Aggregation and Orientation in
Light-emitting Polymer Nanofibers 251
5.2.2 Polarization Properties 254
5.2.3 Light-emission Tunability 256
5.2.4 Other Properties of Light in and from
Nanofibers 262
5.3 Polymer Nanofiber-based Optoelectronics 266
5.3.1 Organic Light-emitting Devices 266
5.3.2 Photo-detectors and Solar Cells 270
5.4 Waveguiding 274
5.5 Lasing 279
5.6 Nanopatterned Nanofibers 282
References 286
Chapter 6 Electrical Properties and Their Applications
6.1 Transport Phenomena in Organic Semiconductors 295
6.1.1 Supramolecular Organization and Electrical
Conduction in Polymers 297
6.2 Nanofibers by Conductive Polymers 300
6.3 Applications in Nanoelectronics 310
6.3.1 Polymer Nanofiber Field-effect Transistors 318
6.3.1.1 P-type Devices 319
6.3.1.2 N-type Devices 323
6.3.1.3 Photo-transistors and Other Devices 323
6.4 Piezoelectricity and Thermo-electricity in Polymer
Nanofibers 324
6.4.1 Piezoelectric Properties 324
6.4.2 Thermo-electric Properties 337
References 338
Contents xiii
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