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ÊéÃû Catalysis µÚ25¾í
×÷ÕßJames J. Spivey, Louisiana State University, USA
Yi-Fan Han, East China University of Science and Technology, Shanghai, China
K. M. Dooley, Louisiana State University, USA
Authors
Jun Bao, University of Science and Technology of China, Hefei, China
A. Beretta, Politecnico di Milano, Italy
Natalia Bo¡§hmer, hte Aktiengesellschaft, Heidelberg, Germany
Mercedes Boronat, Instituto de Tecnolog?¡äa Qu?¡ämica, Valencia, Spain
Uwe Burghaus, North Dakota State University, USA
De Chen, Norwegian University of Science and Technology, Norway
A. Donazzi, Politecnico di Milano, Italy
Xuezhi Duan, East China University of Science and Technology, China
P. Forzatti, Politecnico di Milano, Italy
Karin Fo¡§ ttinger, Vienna University of Technology, Austria
Cornelia Futter, hte Aktiengesellschaft, Heidelberg, Germany
G. Groppi, Politecnico di Milano, Italy
Andreas Kuschel, hte Aktiengesellschaft, Heidelberg, Germany
M. Maestri, Politecnico di Milano, Italy
Eko Prasetyo, hte Aktiengesellschaft, Heidelberg, Germany
Thomas Roussie` re, hte Aktiengesellschaft, Heidelberg, Germany
Stephan A. Schunk, hte Aktiengesellschaft, Heidelberg, Germany
E. Tronconi, Politecnico di Milano, Italy
Noritatsu Tsubaki, University of Toyama, Japan
Xinggui Zhou, East China University of Science and Technology, China
³ö°æÉç»Ê¼Ò»¯Ñ§»á
Ò³Êý 258
ISBN: 978-1-84973-578-0
DOI: 10.1039/9781849737203
ISSN: 0140-0568
Ŀ¼Gaining insight into the kinetics of partial oxidation of light
hydrocarbons on Rh, through a multiscale methodology based on
advanced experimental and modeling techniques
1
A. Beretta, A. Donazzi, G. Groppi, M. Maestri, E. Tronconi and
P. Forzatti
1 Introduction 1
2 The severity of the CPO process 3
3 Experimental tools for the kinetic investigation of the CPO
of CH4 and light hydrocarbons under isothermal
conditions: reactor designs
4
4 A theoretical tool for the kinetic investigation: microkinetic
scheme of CH4 CPO on Rh
13
5 Experimental tools for the kinetic investigation of CH4
CPO in short contact time adiabatic reformers
19
6 Modeling of CPO short contact time adiabatic reformers 29
7 Case studies: analysis of spatially resolved measurements in
adiabatic short contact time CPO reactors
30
8 Optimization of the thermal behavior of short contact time
CPO reformers
38
9 Summary and open issues 41
References 45
Cover
Image provided courtesy of
computational science company
Accelrys (www.accelrys.com).
An electron density isosurface mapped
with the electrostatic potential for an
organometallic molecule. This shows the
charge distribution across the surface of
the molecule with the red area showing
the positive charge associated with the
central metal atom. Research carried
out using Accelrys Materials Studioss.
Catalysis, 2013, 25, ix¨Cxi | ix
c The Royal Society of Chemistry 2013
Downloaded
Published on 11 March 2013 on http://pubs.rsc.org | doi:10.1039/9781849737203-FP009
Theoretical tools for studying gold nanoparticles as catalysts for
oxidation and hydrogenation reactions
50
Mercedes Boronat
1 Introduction 50
2 Oxidation reactions 51
3 Hydrogenation reactions 62
4 Conclusions 72
Acknowledgements 73
References 73
PdZn based catalysts: connecting electronic and geometric structure
with catalytic performance
77
Karin Fo¡§ttinger
1 Introduction 77
2 Preparation, structural and electronic properties 78
3 Catalytic properties in selected applications 94
4 Conclusions and outlook 112
References 113
Structural manipulation of the catalysts for ammonia decomposition 118
Xuezhi Duan, Xinggui Zhou and De Chen
1 Introduction 118
2 Ru-based catalysts 119
3 Ni-based catalysts 126
4 Fe-based catalysts 130
5 Bimetallic catalysts 134
6 Conclusions and perspectives 135
Acknowledgements 136
References 136
Applications of electron beam lithography in surface science and
catalysis ¨C model-nano-array catalysts
141
Uwe Burghaus
1 Introduction 141
2 Nano fabrication of NAC: an example 151
3 UHV sample cleaning and sample stability 152
4 Characterization of morphology and chemical composition 154
5 Physical properties 154
6 Chemical properties and applications in surface chemistry 157
x | Catalysis, 2013, 25, ix¨Cxi
Downloaded
Published on 11 March 2013 on http://pubs.rsc.org | doi:10.1039/9781849737203-FP009
View Online
7 Non-catalytic applications 163
8 Summary 163
Abbreviations 164
Short glossary of related nanofabrication techniques 165
Acknowledgments 167
References 168
High throughput technology: approaches of research in homogeneous
and heterogeneous catalysis
172
Stephan A. Schunk, Natalia Bo¡§hmer, Cornelia Futter,
Andreas Kuschel, Eko Prasetyo and Thomas Roussie`re
1 Introduction 172
2 Homogeneous catalysis 174
3 Heterogeneous catalysis 188
4 Conclusion 207
Acknowledgement 207
References 207
Core-shell catalysts and bimodal catalysts for Fischer-Tropsch
synthesis
216
Jun Bao and Noritatsu Tsubaki
1 Introduction 216
2 Core-shell catalysts for direct synthesis of isoparaffins from
syngas: spatial-confinement effects and shape selectivity
218
3 Bimodal catalysts for Fischer-Tropch synthesis: chemical
and spatial effects
227
4 Conclusions 243
Acknowledgements 243
References 243
Catalysis¡ï¡ï¡ï¡ï¡ï¡ï¡ï2014Êé¼®³¬¼¶ÌûÒ»ËÄÎå¡¶´ß»¯¼Á¡·µÚ25¾í¸ßÇåÊé¼®
(Specialist periodical report) James J Spivey_ Yi-Fan Han_ K  M Dooley-Cata.jpg


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