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ÎÄÕÂÃû³Æ£ºSynthesis and characterization of novel 2,7-carbazole derivatives for blue light-emitting diodes.
ÆÚ¿¯Ãû£ºJ Mater Sci: Mater Electron
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ÎÄÏ×ÀàÐÍ:Article

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Èë²ØºÅ: WOS:000333050400056

ISSN: 0957-4522

µç×Ó ISSN: 1573-482X


EI

Accession number:
       

20141417533549
         
Title:
        Synthesis and characterization of novel 2,7-carbazole derivatives for blue light-emitting diodes
         
Authors:
        Li, Jingtong1; Liu, Ransheng1 Email author rsliu@163.com; Zhao, Zengdian1 Email author zdz1266@126.com; Zhou, Ziyan1
          Author affiliation:         1 School of Chemical Engineering, Shandong University of Technology, Zibo 255049, China
         
Corresponding author:
        Liu, R. (rsliu@163.com)
         
Source title:
        Journal of Materials Science: Materials in Electronics
         
Abbreviated source title:
        J Mater Sci Mater Electron
         
Volume:
        25
         
Issue:
        4
         
Issue date:
        April 2014
         
Publication year:
        2014
         
Pages:
        1970-1975
         
Language:
        English
         
ISSN:
        09574522
         
E-ISSN:
        1573482X
         
Document type:
        Journal article (JA)
         
Publisher:
        Springer New York LLC
         
Abstract:
        Two 2,7-carbazole based low molecular weight derivatives, 9-hexyl-N 2,N 2,N 7,N 7-tetraphenyl-carbazole- 2,7-diamine (TPCA) and 9-hexyl-9H-9,2:7,9-tercarbazole (HTC), were synthesized by Buchwald and Ullmann coupling reactions, respectively. The optical, electrochemical and thermal properties of this two analogous small molecule hosts have been characterized. The HOMO level of TPCA and HTC were -5.25 and -5.29 eV indicating good hole-transporting properties. Both of the compounds emit deep blue light peaked at 410 and 428 nm in solid state. According to the measurement, the luminescence quantum yield of TPCA is 0.98, almost 1.7 times higher than that of HTC (0.59) in dilute THF solution. The geometrical and electronic properties of the compounds were studied using density functional theory calculations. The studies mentioned above indicate that both TPCA and HTC are suitable for active materials of blue light-emitting diodes. © 2014 Springer Science+Business Media New York.
         
Number of references:
        17
         
Main heading:
        Light emitting diodes
         
Controlled terms:
        Chemical bonds  -  Electronic properties  -  Polycyclic aromatic hydrocarbons  -  Supercomputers
         
Uncontrolled terms:
        2 , 7-carbazole derivatives  -  Blue light-emitting  -  Hole-transporting property  -  Low molecular weight  -  Luminescence quantum yields  -  Small molecules  -  Synthesis and characterizations  -  Ullmann coupling reaction
         
Classification code:
        701.1 Electricity: Basic Concepts and Phenomena -  722.4 Digital Computers and Systems -  741.1 Light/Optics -  801.4 Physical Chemistry -  804.1 Organic Compounds
          DOI:         10.1007/s10854-014-1831-4
         
Database:
        Compendex
                  Compilation and indexing terms, © 2013 Elsevier Inc.
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