| 查看: 1657 | 回复: 15 | ||
| 【奖励】 本帖被评价11次，作者crystalccdc增加金币 10 个 | ||
| 当前主题已经存档。 | ||
[资源]
2008 Yaghi "science"最新paper及review
|
||
|
High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO2 Capture Rahul Banerjee,1* Anh Phan,1 Bo Wang,1 Carolyn Knobler,1 Hiroyasu Furukawa,1 Michael O’Keeffe,2 Omar M. Yaghi1* A high-throughput protocol was developed for the synthesis of zeolitic imidazolate frameworks (ZIFs). Twenty-five different ZIF crystals were synthesized from only 9600 microreactions of either zinc(II)/cobalt(II) and imidazolate/imidazolate-type linkers. All of the ZIF structures have tetrahedral frameworks: 10 of which have two different links (heterolinks), 16 of which are previously unobserved compositions and structures, and 5 of which have topologies as yet unobserved in zeolites. Members of a selection of these ZIFs (termed ZIF-68, ZIF-69, and ZIF-70) have high thermal stability (up to 390°C) and chemical stability in refluxing organic and aqueous media. Their frameworks have high porosity (with surface areas up to 1970 square eters per gram), and they exhibit unusual selectivity for CO2 capture from CO2/CO mixtures and extraordinary capacity for storing CO2: 1 liter of ZIF-69 can hold ~83 liters of CO2 at 273 kelvin under ambient pressure. [ Last edited by crystalccdc on 2008-2-26 at 06:44 ] |
回复此楼» 猜你喜欢
天津理工大学
已经有0人回复
-
台州学院有序多孔材料团队最后冲刺，同学们别错过哦，请速联系！
已经有0人回复
-
无机化学论文润色/翻译怎么收费?
已经有285人回复
-
江西科技师范大学物理化学课题组接收调剂生，名额还有，速来
已经有0人回复
-
求碳酸钠和碳酸氢钠的晶胞结构图或晶体结构图
已经有0人回复
-
求碳酸钠和碳酸氢钠的晶胞结构图或晶体结构图
已经有0人回复
-
江西科技师范大学物理化学课题组接收调剂生，12点开启，速来
已经有0人回复
-
【2026 考研调剂】哈尔滨工程大学 招收学硕调剂生（英语一、数学一）
已经有0人回复
2楼2008-02-26 09:33:43
3楼2008-02-26 10:50:00
4楼2008-02-26 13:43:07
5楼2008-10-09 16:52:53
6楼2008-10-11 00:00:46
7楼2008-10-11 07:21:43
8楼2008-10-12 10:27:00
9楼2008-10-13 00:27:23
10楼2008-10-13 10:10:45
简单回复
sxm1983051611楼
2008-10-26 16:35
回复
谢谢分享！
