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Flame retardant epoxy resin based on bisphenol A epoxy resin modified by phosphoric acid C Jiao, J Zhuo, X Chen, S Li, H Wang Journal of thermal analysis and calorimetry 114 (1), 253-259 1 2013 |
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oceanpolymer: ½ð±Ò+5, ¡ï¡ï¡ï¡ï¡ï×î¼Ñ´ð°¸, thank you 2014-03-13 09:00:45
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±êÌâ: Flame retardant epoxy resin based on bisphenol A epoxy resin modified by phosphoric acid ×÷Õß: Jiao, CM (Jiao, Chuanmei); Zhuo, JL (Zhuo, Jinlong); Chen, XL (Chen, Xilei); Li, SX (Li, Shaoxiang); Wang, HJ (Wang, Huajin) À´Ô´³ö°æÎï: JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY ¾í: 114 ÆÚ: 1 Ò³: 253-259 DOI: 10.1007/s10973-012-2867-4 ³ö°æÄê: OCT 2013 ÔÚ Web of Science Öеı»ÒýƵ´Î: 1 ±»ÒýƵ´ÎºÏ¼Æ: 1 ÒýÓõIJο¼ÎÄÏ×Êý: 20 ÕªÒª: Flame retardant epoxy resin (FREP) were synthesized from phosphoric acid and bisphenol A epoxy resin (BAEP). The structure of the FREP was characterized using FTIR and P-31 NMR. Then, several FREP/BAEP mass ratios were used to obtain materials with different phosphorus contents. The properties of the thermosetting materials were evaluated by limiting oxygen index, UL 94, cone calorimeter test, and thermogravimetric analysis. The results showed that the heat release rates and smoke production rates decreased greatly, and char residue increased with the increasing of FREP. It indicates that good flame retardant properties are related to the formation of a protective phosphorus-rich char layer. Èë²ØºÅ: WOS:000325075600029 ÓïÖÖ: English ÎÄÏ×ÀàÐÍ: Article ×÷Õ߹ؼü´Ê: Epoxy resin; Flame retardant; Phosphoric acid KeyWords Plus: HYPERBRANCHED POLYPHOSPHATE ESTER; THERMAL-DECOMPOSITION; FLAMMABILITY; DEGRADATION; SYSTEMS µØÖ·: [Jiao, Chuanmei; Zhuo, Jinlong; Chen, Xilei; Li, Shaoxiang] Qingdao Univ Sci & Technol, Coll Environm & Safety Engn, Qingdao 266042, Shandong, Peoples R China. [Wang, Huajin] Marine Chem Res Inst, Qingdao 266071, Shandong, Peoples R China. ͨѶ×÷ÕßµØÖ·: Chen, XL (ͨѶ×÷Õß),Qingdao Univ Sci & Technol, Coll Environm & Safety Engn, Qingdao 266042, Shandong, Peoples R China. µç×ÓÓʼþµØÖ·: xilei_chen@foxmail.com ×÷Õßʶ±ðºÅ: ×÷Õß ResearcherID ºÅ ORCID ºÅ Jiao, Chuanmei A-1133-2014 Chen, Xilei M-8864-2013 ³ö°æÉÌ: SPRINGER ³ö°æÉ̵ØÖ·: VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS Web of Science Àà±ð: Chemistry, Analytical; Chemistry, Physical Ñо¿·½Ïò: Chemistry IDS ºÅ: 226ZE ISSN: 1388-6150 29 ×Ö·ûµÄÀ´Ô´³ö°æÎïÃû³ÆËõд: J THERM ANAL CALORIM ISO À´Ô´³ö°æÎïËõд: J. Therm. Anal. Calorim. À´Ô´³ö°æÎïÒ³Âë¼ÆÊý: 7 »ù½ð×ÊÖúÖÂл: »ù½ð×ÊÖú»ú¹¹ ÊÚȨºÅ National Basic Research Program of China (973 Program) 2012CB724609 National Natural Science Foundation of China 51206084 Out-standing Young Scientist Research Award Fund from Shandong Province BS2011CL018 The authors gratefully acknowledge the National Basic Research Program of China (973 Program, No. 2012CB724609), National Natural Science Foundation of China (No. 51206084) and the Out-standing Young Scientist Research Award Fund from Shandong Province (BS2011CL018). |
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