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贡献Angew Chem最新的两篇构筑螺旋结构的文章
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Supramolecular Helix-to-Helix Induction: A 3D Anionic Framework Containing Double-Helical Strands Templated by Cationic Triple-Stranded Cluster Helicates All wrapped up: Supramolecular polymeric helices were fabricated by using cluster helicates as templates. The helicity of the template (see picture; gold spheres: Ni or Zn; blue spheres: O), upon hydrothermal treatment with CuSCN (gray spheres), is transferred to the strands of the resulting copper-based coordination polymer, which is wrapped around the helicate units in the final product. Quadruple and Double Helices of 8-Fluoroquinoline Oligoamides Winding and rewinding: How many times can helical aromatic oligomers wind around one another? At least four, as judged by the aggregation behavior of oligoamides based on 8-fluoroquinoline (see scheme depicting the formation of a quadruple helix; red spheres: sites in the hollow space partially occupied by water molecules). [ Last edited by pauldli on 2008-2-14 at 23:51 ] |
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