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| The crystal structures of the complexes were determined and indicate that in the solid state the complex adopts a slightly distorted octahedral environment of the imine N and hydroxo O with the two axial ligands. The electrochemical reduction of these complexes at a glassy carbon electrode in acetonitrile solution indicates that the first reduction process corresponding to Mn III–Mn II is electrochemically quasi-reversible. Thermal stability of these complexes was determined by TG and DTG. Layers of these complexes were formed on nanostructure zinc oxide thin film and a red shift was observed when zinc oxide thin film is modified by complex |
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RXMCDM: 金币+1, 多谢应助!但好像求助者是要求翻成中文! 2014-03-05 10:13:50
RXMCDM: 金币+1, 多谢应助!但好像求助者是要求翻成中文! 2014-03-05 10:13:50
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The crystal structures of the complexes were determined, and the results revealed that in the solid state, a slightly distorted octahedral coordination was adopted with the imine N and hydroxo O in the two axial ligands. The electrochemical reduction of the complex at a glassy carbon electrode in acetonitrile indicated that the first reduction process corresponding to Mn III–Mn II was electrochemically quasi-reversible. Thermal stability of these complexes was determined by TG and DTG. Layers of these complexes were formed on nanostructure zinc oxide thin film and a red shift was observed when the zinc oxide thin film is modified by these complexes. 还是过去时好些。 |

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