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[资源] 【Chem. Rev.】 2014 Chlorotrifluoroethylene 三氟氯乙烯共聚物综述已有4人参与

(Co)polymers of Chlorotrifluoroethylene: Synthesis, Properties, and Applications

http://pubs.acs.org/doi/abs/10.1021/cr2002933

由于F原子比较小以及强的负电性，C-F键使得含氟聚合物具有了很多优于其他聚合物材料的特性，使其在很多领域具有很好的应用前景

Fluorinated polymers are niche macromolecules that attract much interest because of the versatility of a wide range of applications. Their use ranges from thermoplastics, elastomers, and plastomers to thermoplastic elastomers as well as from semicrystalline to fully amorphous. Furthermore, largely due to the properties of the fluorine element (strong electronegativity, low polarizability, and small van der Waals radius (1.32 Å

) and to the strong C−F bonds (485 kJ mol−1), they exhibit unique and remarkable properties. Hence, fluoropolymers with a high fluorine content exhibit exceptional properties. These include high chemical, thermal, aging, and weather resistance as well as outstanding inertness to hydrocarbons, solvents, acids, and bases. Other highly desirable properties include low dielectric constant, low surface energy (water and oil repellency), low flammability, low refractive index, and low moisture absorption. Furthermore, the high strength of the C−F bond in these polymers has a critical impact on their great resistance to both hydrolytic and oxidation stability.

该综述在第一部分总结了CTFE的不同合成方法；第二部分综述了CTFE的二元以及三元共聚合成；第三部分也就是最主要的部分各种不同的CTFE二元共聚物的自由基聚合；第四部分讲了如何设计和改性CTFE的二元共聚物；最后一部分给出了CTFE-based 聚合物的应用。

【Chem. Rev.】 2014 Chlorotrifluoroethylene 三氟氯乙烯共聚物综述

屏幕快照 2014-02-23 23.39.12.png

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附件 1 : (Co)polymers_of_Chlorotrifluoroethylene-_Synthesis,_Properties,_and_Applications.pdf

2014-02-24 06:53:04, 8.2 M