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(Co)polymers of Chlorotrifluoroethylene: Synthesis, Properties, and Applications http://pubs.acs.org/doi/abs/10.1021/cr2002933 ÓÉÓÚFÔ×ӱȽÏСÒÔ¼°Ç¿µÄ¸ºµçÐÔ£¬C-F¼üʹµÃº¬·ú¾ÛºÏÎï¾ßÓÐÁ˺ܶàÓÅÓÚÆäËû¾ÛºÏÎï²ÄÁϵÄÌØÐÔ£¬Ê¹ÆäÔںܶàÁìÓò¾ßÓкܺõÄÓ¦ÓÃǰ¾° Fluorinated polymers are niche macromolecules that attract much interest because of the versatility of a wide range of applications. Their use ranges from thermoplastics, elastomers, and plastomers to thermoplastic elastomers as well as from semicrystalline to fully amorphous. Furthermore, largely due to the properties of the fluorine element (strong electronegativity, low polarizability, and small van der Waals radius (1.32 Å ) and to the strong C−F bonds (485 kJ mol−1), they exhibit unique and remarkable properties. Hence, fluoropolymers with a high fluorine content exhibit exceptional properties. These include high chemical, thermal, aging, and weather resistance as well as outstanding inertness to hydrocarbons, solvents, acids, and bases. Other highly desirable properties include low dielectric constant, low surface energy (water and oil repellency), low flammability, low refractive index, and low moisture absorption. Furthermore, the high strength of the C−F bond in these polymers has a critical impact on their great resistance to both hydrolytic and oxidation stability.¸Ã×ÛÊöÔÚµÚÒ»²¿·Ö×ܽáÁËCTFEµÄ²»Í¬ºÏ³É·½·¨£»µÚ¶þ²¿·Ö×ÛÊöÁËCTFEµÄ¶þÔªÒÔ¼°ÈýÔª¹²¾ÛºÏ³É£»µÚÈý²¿·ÖÒ²¾ÍÊÇ×îÖ÷ÒªµÄ²¿·Ö¸÷ÖÖ²»Í¬µÄCTFE¶þÔª¹²¾ÛÎïµÄ×ÔÓÉ»ù¾ÛºÏ£»µÚËIJ¿·Ö½²ÁËÈçºÎÉè¼ÆºÍ¸ÄÐÔCTFEµÄ¶þÔª¹²¾ÛÎ×îºóÒ»²¿·Ö¸ø³öÁËCTFE-based ¾ÛºÏÎïµÄÓ¦ÓᣠÆÁÄ»¿ìÕÕ 2014-02-23 23.39.12.png |
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) and to the strong C−F bonds (485 kJ mol−1), they exhibit unique and remarkable properties. Hence, fluoropolymers with a high fluorine content exhibit exceptional properties. These include high chemical, thermal, aging, and weather resistance as well as outstanding inertness to hydrocarbons, solvents, acids, and bases. Other highly desirable properties include low dielectric constant, low surface energy (water and oil repellency), low flammability, low refractive index, and low moisture absorption. Furthermore, the high strength of the C−F bond in these polymers has a critical impact on their great resistance to both hydrolytic and oxidation stability.
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