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Ashin3351银虫 (小有名气)
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[求助]
求助翻译成中文，谢谢
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In theory,instead, implementing chirality directly at the reactive metal center−exploiting the metal as a source of centrochirality− would be highly attractive since the close proximity of the metal to the coordinating substrate promises a highly effective transfer of chirality during the asymmetric induction.However, a considerable obstacle for the realization of such reactive chiral-at-metal asymmetric catalysts constitutes the retention of the relative and absolute metal-centered configuration during the reaction, since the coordination number at the metal varies during each catalytic cycle and thereby provides ample opportunities for the stereochemistry of the metal to scramble. |
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2楼2014-02-16 23:40:34
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3楼2014-02-17 00:31:32