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zyxr

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根据配合物1的晶体结构参数,Mn(1)-O(2)-Mn(2),Mn(3)-O(4)-Mn(2)和Mn(4)-O(8)-Mn(2)的键角很接近,可知Mn(1),Mn(3)和Mn(4)与Mn(2)之间的磁耦合常数J应该很近,假定它们相等是合理的(J1)。
Based on the the crystal structure parameters of the complex 1, the bond angles of Mn(1)-O(2)-Mn(2) and Mn(3)-O(4)-Mn(2) are close to the bond angle of Mn(4)-O(8)-Mn(2), there are quite modest differences between the magnetic coupling constants of Mn(1), Mn(3) and Mn(4) respectively with Mn(2), hence, we hypothesize one J1 value between them is reasonable.
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RXMCDM

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2楼: Originally posted by phu_grassman at 2014-01-16 20:52:47
According to the crystal parameters, the bond angles of Mn (1)-O (2)-Mn (2), Mn (3)-O (4)-Mn (2) and Mn (3)-O (4)-Mn (2) are close to each other, which indicates that the magnetic coupling constants  ...

According to the crystal parameters, the bond angles of Mn (1)-O (2)-Mn (2), Mn (3)-O (4)-Mn (2) and  Mn(4)-O(8)-Mn(2) are close to each other, which indicates that the magnetic coupling constants between Mn (1), Mn (3), Mn (4) and Mn(2) are comparable. Hence, it’s reasonable to suppose that they have equal J1 value.
3楼2014-01-21 00:31:17
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phu_grassman

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真强必胜: 金币+1, good 2014-01-17 13:24:08
zyxr(RXMCDM代发): 金币+10, 最佳答案! 2014-01-21 00:31:57
RXMCDM: 翻译EPI+1 2014-01-21 00:32:02
According to the crystal parameters, the bond angles of Mn (1)-O (2)-Mn (2), Mn (3)-O (4)-Mn (2) and Mn (3)-O (4)-Mn (2) are close to each other, which indicates that the magnetic coupling constants between Mn (1), Mn (3), Mn (4) and Mn(2) are comparable. Hence, it’s reasonable to suppose that they have equal J1 value.
2楼2014-01-16 20:52:47
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zyxr

金虫 (正式写手)

引用回帖:
3楼: Originally posted by RXMCDM at 2014-01-21 00:31:17
According to the crystal parameters, the bond angles of Mn (1)-O (2)-Mn (2), Mn (3)-O (4)-Mn (2) and  Mn(4)-O(8)-Mn(2) are close to each other, which indicates that the magnetic coupling constants b ...

答案和楼上没有区别啊,你是不是忘记修改就发表了

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4楼2014-01-21 09:19:59
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RXMCDM

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4楼: Originally posted by zyxr at 2014-01-21 09:19:59
答案和楼上没有区别啊,你是不是忘记修改就发表了
...

楼上帮你修改的时候有个地方复制错了,不是改其答案!
5楼2014-01-21 22:53:54
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