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RXMCDM: ½ð±Ò+1, ¶àлӦÖú£¡ 2014-01-15 13:10:50
zyxr(RXMCDM´ú·¢): ½ð±Ò+18, ×î¼Ñ´ð°¸£¡ 2014-01-22 00:43:41
RXMCDM: ·ÒëEPI+1 2014-01-22 00:43:51
RXMCDM: ½ð±Ò+1, ¶àлӦÖú£¡ 2014-01-15 13:10:50
zyxr(RXMCDM´ú·¢): ½ð±Ò+18, ×î¼Ñ´ð°¸£¡ 2014-01-22 00:43:41
RXMCDM: ·ÒëEPI+1 2014-01-22 00:43:51
| among the known single molecular magnets, h2sae based and their derivative MN4 molecular clusters possess tunable structures via the bridged Cl-ions. As it is quite versatile to HN3 ion, their coordination compounds have variable magnetic properties. A case in point is, as recently reported, the introduciton of HN3 to Mn coordination compound can result in, among others, a single molecular magnet |
2Â¥2014-01-15 13:06:32
zyxr
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The O-containing ligand used for the synthesis of polynuclear molecular clusters not only include classical carboxylic acid, but also include Schiff base ligand H2sae (H2sae=2-salicylidene-amino-1-ethanol), Phenolic ligands Hhmp (Hhmp = 2-hydroxymethylpyridine) and their derivatives, which manifest more diversity in assembly multinuclear complex because they both feature nitrogen and oxygen atoms ×é×°ÕâЩ¶àºË·Ö×Ӵصĺ¬ÑõÅäÌå³ý¾µäµÄôÈËáÍ⣬»¹°üÀ¨Ï£·ò¼îÅäÌåH2sae £¨H2sae = 2-salicylidene-amino-1-ethanol£©¼°·ÓÀàÅäÌåHhmp(Hhmp = 2-hydroxymethylpyridine£©¼°ÆäÑÜÉúÎÕâÀàÅäÌåͬʱº¬µª¼°Ñõ£¬ÔÚ×é×°¶àºËÅäºÏÎï·½Ãæ¾ßÓкܴóµÄÁé»îÐÔ¡£ Äã°ïÎÒ¿´ÏÂÎÒÕâ¾äÓ¢Îıí´ïµÄÒâ˼ÊÇ·ñÕýÈ·£¿Ð»Ð»Á˰¡ |
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