| 查看: 10167 | 回复: 322 | ||||
| 本帖产生 1 个 MN-EPI ，点击这里进行查看 | ||||
| 当前只显示满足指定条件的回帖，点击这里查看本话题的所有回帖 | ||||
xiejf专家顾问 (文学泰斗)
|
[资源]
厦门大学Acc. Chem. Res.最新综述：具有高能晶面的金属氧化物微纳晶体及其应用
|
|||
|
最新一期的Acc. Chem. Res.杂志刊发了由厦门大学谢兆雄教授课题组与郑兰荪院士撰写的题为High-Energy-Surface Engineered Metal Oxide Micro- and Nanocrystallites and Their Applications的研究性综述，介绍了具有高能晶面的金属氧化物微纳晶体及其应用这一领域的最新进展。文章11页，引文53篇。 Because many physical and chemical processes occur at surfaces, surface atomic structure is a critical factor affecting the properties of materials. Due to the presence of high-density atomic steps and edges and abundant unsaturated coordination sites, micro- and nanocrystallites with high-energy surfaces usually exhibit greater reactivity than those with low-energy surfaces. However, high-energy crystal surfaces are usually lost during crystal growth as the total surface energy is minimized. Therefore, the selective exposure of high-energy facets at the surface of micro- and nanocrystallites is an important and challenging research topic. Metal oxides play important roles in surface-associated applications, including catalysis, gas sensing, luminescence, and antibiosis. The synthesis of metal oxide micro- and nanocrystallites with specific surfaces, particularly those with high surface energies, is more challenging than the synthesis of metal crystals due to the presence of strong metal–oxygen bonds and diverse crystal structures. In this Account, we briefly summarize recent progress in the surface-structure-controlled synthesis of several typical metal oxide micro- and nanocrystallites, including wurtzite ZnO, anatase TiO2, rutile SnO2, and rocksalt-type metal oxides. We also discuss the improvement of surface properties, focusing on high-energy surfaces. Because of the huge quantity and diverse structure of metal oxides, this Account is not intended to be comprehensive. Instead, we discuss salient features of metal oxide micro- and nanocrystallites using examples primarily from our group. We first discuss general strategies for tuning the surface structure of metal oxide micro- and nanocrystallites, presenting several typical examples. For each example, we describe the basic crystallographic characteristics as well as the thermodynamic (i.e., tuning surface energy) or kinetic (i.e., tuning reaction rates) strategies we have used to synthesize micro- and nanocrystallites with high surface energies. We discuss the structural features of the specific facets and analyze the basis for the enhanced performance of the metal oxide micro- and nanocrystallites in water splitting, the degradation of organic pollutants, gas sensing, catalysis, luminescence, and antibiosis. Finally, we note the future trends in high-energy-facet metal oxide micro- and nanocrystallite research. A comprehensive understanding of the properties of metal oxide micro- and nanocrystallites with high-energy crystal surfaces and related synthetic strategies will facilitate the rational design of functional nanomaterials with desired characteristics. /  ar-2013-00092x_0008.gif |
回复此楼» 本帖附件资源列表
-
欢迎监督和反馈：小木虫仅提供交流平台，不对该内容负责。
本内容由用户自主发布，如果其内容涉及到知识产权问题，其责任在于用户本人，如对版权有异议，请联系邮箱：xiaomuchong@tal.com - 附件 1 : High-Energy-Surface_Engineered_Metal_Oxide_Micro-_and_Nanocrystallites_and_Their_Applications.pdf
2013-12-21 12:25:57, 1.8 M
» 本帖已获得的红花（最新10朵）
1002701032» 猜你喜欢
有关蒙脱土阳离子交换的问题！求助！
已经有2人回复
-
荧光粉分散在水溶液里经过光照射后可以看到荧光
已经有2人回复
-
金属材料论文润色/翻译怎么收费?
已经有258人回复
-
碳量子点
已经有0人回复
-
请教关于高温固相法合成氟取代氧化物的细节
已经有15人回复
-
【新加坡】【南洋理工大学】招聘博士后一名（Research Fellow）
已经有43人回复
-
钙钛矿 博士申请
已经有5人回复
-
求助 光强I=(ρνω^2A^2)/2 是怎么推导出来的 ？
已经有0人回复
-
钙钛矿 博士申请
已经有5人回复
-
25年申博，求导收留（24/25）
已经有1人回复
305楼2015-12-14 23:00:21
9楼2013-12-21 15:42:01
简单回复
w_wwb3楼
2013-12-21 13:33
回复
五星好评 顶一下，感谢分享！
2013-12-21 13:34
回复
五星好评 顶一下，感谢分享！
xzb3285楼
2013-12-21 13:53
回复
五星好评 顶一下，感谢分享！
马踏冰河6楼
2013-12-21 13:59
回复
五星好评 顶一下，感谢分享！
牛虻吹泡泡7楼
2013-12-21 14:07
回复
五星好评 顶一下，感谢分享！
huwei028楼
2013-12-21 14:40
回复
五星好评 顶一下，感谢分享！
41439931510楼
2013-12-21 15:58
回复
五星好评 顶一下，感谢分享！
jjseu11楼
2013-12-21 16:29
回复
五星好评 顶一下，感谢分享！
Solar_WB12楼
2013-12-21 17:08
回复
五星好评 顶一下，感谢分享！
yuedanhappy13楼
2013-12-21 17:10
回复
五星好评 顶一下，感谢分享！
20