24小时热门版块排行榜    

Znn3bq.jpeg
查看: 848  |  回复: 4
当前主题已经存档。
当前只显示满足指定条件的回帖,点击这里查看本话题的所有回帖

MnO

银虫 (正式写手)

[交流] 有用钛酸四异丙醇酯(TTIP)制二氧化钛的请进!

一般国内的都是用钛酸四丁醇酯制二氧化钛

但外文文献好多都是用钛酸四异丙醇酯做的,不知道有没有用这个做的,不知道两者什么差别啊,特别是比表面积啊?

看到一文献用钛酸四丁醇酯(TTIP)直接滴加到水中,搅拌,陈化形成溶胶,怎么可能啊?钛酸四丁酯一滴到水中就沉淀了,不知道两者什么区别啊?
Titanium tetraisopropoxide (TTIP) was used as a titanium
source. NH4F was used as a precursor of the dopant. NH4F
was dissolved in pure water and then TTIP (0.0125 mol) was
added dropwise to 100 mL of the H2O-NH4F mixed solution
under vigorous stirring at room temperature. The atomic ratios
of F to Ti, which hereafter was designated as RF, were 0, 0.5,
1, 3, 5, 10, and 20 nominal atomic % (at. %). Sol samples???????
obtained by the hydrolysis process were aged in a closed beaker
at room temperature for 24 h uto further hydrolyze the TTIP
and obtain monodisperse TiO2 particles. After aging, these
samples were dried at 100 °C for about 8 h in air to vaporize
water and alcohol in the gels and then ground to fine powders
to obtain xerogel samples. The xerogel samples were calcined
at temperatures of 400, 500, 600, and 700 °C in air for 1 h
怎么可能是溶胶啊 ?

[ Last edited by MnO on 2007-12-3 at 22:39 ]
回复此楼
已阅   回复此楼   关注TA 给TA发消息 送TA红花 TA的回帖

celiacelia1985

银虫 (正式写手)

我也是想知道,这两种前驱物有什么差别
5楼2007-12-04 09:48:16
已阅   回复此楼   关注TA 给TA发消息 送TA红花 TA的回帖
查看全部 5 个回答

ratio

荣誉版主 (职业作家)

已暂停一切论坛内交流

优秀区长优秀版主


eric2004(金币+1,VIP+0):多谢您热心应助!
应该是先加无水乙醇,而后滴加少量水,可以形成sol的
2楼2007-12-03 23:31:06
已阅   回复此楼   关注TA 给TA发消息 送TA红花 TA的回帖

suohaiyun

铁虫 (小有名气)


eric2004(金币+1,VIP+0):多谢应助!支持新虫参与讨论!
用无水乙醇溶解,并且得加入水解抑制剂,三乙醇胺,否则很粘稠,难制备.
3楼2007-12-04 08:45:58
已阅   回复此楼   关注TA 给TA发消息 送TA红花 TA的回帖

MnO

银虫 (正式写手)

我也说用钛酸四丁酯要形成溶胶就要加无水乙醇,也要加醋酸做抑制剂,可是不知道为什么这篇文献用钛酸四异丙醇酯为什么做的这么简单,我也没用过,查了些文献看到别人也有用TTIP,也要加醇,抑制剂之类的。
这篇文献这样做出的比表面积好大,我想做高比表面积的东西,谁帮我完善一下这个实验方案啊?
多谢了!!!!!!!
4楼2007-12-04 09:44:15
已阅   回复此楼   关注TA 给TA发消息 送TA红花 TA的回帖
普通表情 高级回复 (可上传附件)
最具人气热帖推荐 [查看全部] 作者 回/看 最后发表
[考研] 一志愿哈工大,初试329,求环境科学与工程调剂! +11 余未辛 2026-04-06 11/550 2026-04-08 15:21 by screening
[考研] 277求调剂 +4 考研调剂lxh 2026-04-06 6/300 2026-04-08 10:40 by 逆水乘风
[考研] 323求调剂 +3 林zlu 2026-04-07 4/200 2026-04-07 23:21 by lbsjt
[考研] 331求调剂 +5 张元一 2026-04-07 6/300 2026-04-07 22:13 by hemengdong
[考研] 312求调剂 +18 gtw1 2026-04-06 20/1000 2026-04-07 18:16 by 蓝云思雨
[考研] 325 调剂 +6 QQ小虾 2026-04-07 6/300 2026-04-07 15:17 by Ccclqqq
[考研] 材料调剂 +17 小刘同学吖吖 2026-04-06 18/900 2026-04-07 11:41 by 诗与自由
[考研] 考研调剂 +5 美丽的youth_ 2026-04-04 6/300 2026-04-06 06:57 by houyaoxu
[考研] 272分求调剂 +4 wangyile2233 2026-04-02 4/200 2026-04-05 22:21 by 286640313
[考研] 22408 总分320,一篇论文二作,两个国三,求调剂 +3 Leomulufu 2026-04-04 5/250 2026-04-05 19:04 by chongya
[考研] 353求调剂 +10 MayUxw1 2026-04-03 10/500 2026-04-05 09:23 by 无际的草原
[考研] 考研调剂 +11 小sun要好运 2026-04-04 11/550 2026-04-05 08:02 by qlm5820
[考研] 313求调剂 +3 海日海日 2026-04-04 3/150 2026-04-05 07:48 by 544594351
[考研] 材料与化工306分找调剂 +23 沧海轻舟e 2026-04-02 27/1350 2026-04-04 21:52 by laoshidan
[考研] 一志愿沪985,326分求调剂 +3 刘墨墨 2026-04-03 3/150 2026-04-04 11:16 by 悲伤的芋头
[考研] 一志愿北京科技大学材料工程085601,求调剂 +17 cdyw 2026-04-02 18/900 2026-04-04 11:14 by w_xuqing
[考研] 工科341分调剂 +3 洛多罗 2026-04-03 3/150 2026-04-03 14:20 by 1753564080
[考研] 285求调剂 +7 AZMK 2026-04-02 9/450 2026-04-03 11:12 by wanwan00
[考研] 一志愿安徽大学0817化学工程与技术,求调剂 +14 我不是只因 2026-04-02 15/750 2026-04-03 09:49 by 蓝云思雨
[考研] 22408 266求调剂 +3 masss11222 2026-04-02 3/150 2026-04-02 18:11 by 笔落锦州
信息提示
请填处理意见