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MnO

银虫 (正式写手)

[交流] 有用钛酸四异丙醇酯(TTIP)制二氧化钛的请进!

一般国内的都是用钛酸四丁醇酯制二氧化钛

但外文文献好多都是用钛酸四异丙醇酯做的,不知道有没有用这个做的,不知道两者什么差别啊,特别是比表面积啊?

看到一文献用钛酸四丁醇酯(TTIP)直接滴加到水中,搅拌,陈化形成溶胶,怎么可能啊?钛酸四丁酯一滴到水中就沉淀了,不知道两者什么区别啊?
Titanium tetraisopropoxide (TTIP) was used as a titanium
source. NH4F was used as a precursor of the dopant. NH4F
was dissolved in pure water and then TTIP (0.0125 mol) was
added dropwise to 100 mL of the H2O-NH4F mixed solution
under vigorous stirring at room temperature. The atomic ratios
of F to Ti, which hereafter was designated as RF, were 0, 0.5,
1, 3, 5, 10, and 20 nominal atomic % (at. %). Sol samples???????
obtained by the hydrolysis process were aged in a closed beaker
at room temperature for 24 h uto further hydrolyze the TTIP
and obtain monodisperse TiO2 particles. After aging, these
samples were dried at 100 °C for about 8 h in air to vaporize
water and alcohol in the gels and then ground to fine powders
to obtain xerogel samples. The xerogel samples were calcined
at temperatures of 400, 500, 600, and 700 °C in air for 1 h
怎么可能是溶胶啊 ?

[ Last edited by MnO on 2007-12-3 at 22:39 ]
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eric2004(金币+1,VIP+0):多谢您热心应助!
应该是先加无水乙醇,而后滴加少量水,可以形成sol的
2楼2007-12-03 23:31:06
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suohaiyun

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eric2004(金币+1,VIP+0):多谢应助!支持新虫参与讨论!
用无水乙醇溶解,并且得加入水解抑制剂,三乙醇胺,否则很粘稠,难制备.
3楼2007-12-04 08:45:58
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MnO

银虫 (正式写手)

我也说用钛酸四丁酯要形成溶胶就要加无水乙醇,也要加醋酸做抑制剂,可是不知道为什么这篇文献用钛酸四异丙醇酯为什么做的这么简单,我也没用过,查了些文献看到别人也有用TTIP,也要加醇,抑制剂之类的。
这篇文献这样做出的比表面积好大,我想做高比表面积的东西,谁帮我完善一下这个实验方案啊?
多谢了!!!!!!!
4楼2007-12-04 09:44:15
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celiacelia1985

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我也是想知道,这两种前驱物有什么差别
5楼2007-12-04 09:48:16
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