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The desired diffusion of excitons towards the organic¨Corganic
interface (process 2) poses stringent requirements on the
thin-film morphology. Exciton diffusion lengths in polymeric
and disordered molecular solids are typically in the range of a
few nanometers or a few tens of nanometers, and increase to
a few hundred nanometers for highly ordered crystalline samples.Consequently, the average spacing of organic heterojunctions
should be on the length scale of the exciton diffusion
lengths. This leads to a laterally structured architecture
with vertically interdigitated separate phases, as shown schematically
in Figure 10b, where every generated exciton should
be able to diffuse towards an organic¨Corganic interface. In reality,
the fabrication of such ideal structures is inherently difficult
with both small-molecular and polymeric materials, in particular
because of the small length scales involved.

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