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[资源] Introduction to Thermoelectricity

Introduction to Thermoelectricity
Contents
List of Symbols .....................................................................xiii
1 The Thermoelectric and Related Effects .................................... 1
1.1 Introduction ............................................................. 1
1.2 Relations Between the Thermoelectric Coefficients .................. 3
1.3 Effects in a Magnetic Field............................................. 5
References ....................................................................... 6
2 Theory of Thermoelectric Refrigeration and Generation................. 7
2.1 The Transport Effects .................................................. 7
2.2 Thermoelectric Refrigerators and Heat Pumps........................ 8
2.3 Thermoelectric Generators ............................................. 13
2.4 Multi-Stage Devices .................................................... 15
2.5 Application of the Thermomagnetic Effects .......................... 17
References ....................................................................... 21
3 Thermoelectric Properties of Metals and Semiconductors ............... 23
3.1 Transport by Electrons ................................................. 23
3.2 Metals and Semiconductors ............................................ 29
3.3 Bipolar Effects .......................................................... 34
3.4 Phonon Conduction..................................................... 36
3.5 Phonon Drag ............................................................ 39
References ....................................................................... 41
4 Optimisation and Selection of Semiconductor Thermoelements ......... 43
4.1 Power Factor ............................................................ 43
4.2 The Materials Parameter, ˇ ............................................ 44
4.3 Mobility and Effective Mass ........................................... 46
4.4 The Lattice Thermal Conductivity in Pure Crystals .................. 47
4.5 The Effect of Temperature ............................................. 50
4.6 The Importance of the Energy Gap .................................... 51
4.7 Non-Parabolic Bands ................................................... 53
x Contents
4.8 ThermomagneticMaterials............................................. 55
4.9 Superconductors as Passive Thermoelements ......................... 60
References ....................................................................... 61
5 Minimising the Thermal Conductivity ...................................... 63
5.1 Semiconductor Solid Solutions ........................................ 63
5.2 Phonon Scattering by Point Defects ................................... 64
5.3 Boundary Scattering .................................................... 70
5.4 Scattering of Electrons and Phonons .................................. 72
5.5 Fine-Grained Material with Large Unit Cells ......................... 74
5.6 Phonon-Glass Electron-Crystal ........................................ 76
References ....................................................................... 78
6 The Improvement of a Specific Material – Bismuth Telluride............ 79
6.1 Pure Bismuth Telluride ................................................. 79
6.2 Band Structure of Bismuth Telluride .................................. 82
6.3 Diffusion in Bismuth Telluride......................................... 86
6.4 Solid Solutions Based on Bismuth Telluride .......................... 87
6.5 Practical Developments ................................................ 90
6.6 Extension of the Temperature Range .................................. 93
6.7 Recent Advances ....................................................... 96
References ....................................................................... 97
7 Methods for the Production of Materials ................................... 99
7.1 General Principles ...................................................... 99
7.2 Growth From the Melt ..................................................100
7.3 Sintering ................................................................105
7.4 Thick and Thin films ...................................................109
References .......................................................................110
8 Measurement Techniques .....................................................113
8.1 General Considerations.................................................113
8.2 Electrical Conductivity .................................................114
8.3 Seebeck Coefficient ....................................................118
8.4 Thermal Conductivity ..................................................121
8.5 Thermal Diffusivity.....................................................126
8.6 The Figure of Merit .....................................................128
8.7 ThermomagneticMeasurements .......................................135
References .......................................................................138
9 Review of ThermoelectricMaterials ........................................139
9.1 Bismuth and Bismuth–Antimony ......................................139
9.2 Lead Telluride and Related Compounds...............................148
9.3 Silicon–Germanium Alloys ............................................151
9.4 Skutterudites and Clathrates ...........................................154
9.4.1 Skutterudites ....................................................154
9.4.2 Clathrates .......................................................156
9.5 Oxides ...................................................................159
9.6 Other ThermoelectricMaterials........................................160
9.6.1 Zinc Antimonide ...............................................160
9.6.2 Half-Heusler Compounds ......................................161
9.6.3 Metal Silicides ..................................................162
9.6.4 Boron Carbide ..................................................163
References .......................................................................164
10 Thermoelectric Modules and Their Application ...........................167
10.1 The Modular Concept ..................................................167
10.2 Heat Transfer Problems ................................................171
10.3 Electrical Contact Resistance ..........................................174
10.4 Applications of the Peltier Effect ......................................176
10.5 Transient Cooling.......................................................179
10.6 Seebeck Devices ........................................................182
References .......................................................................188
11 Transverse Devices ............................................................191
11.1 Features of Transverse Coolers and Generators .......................191
11.2 Synthetic Transverse Thermoelements ................................192
11.3 Materials for Transverse Thermoelements ............................195
11.4 Alternative Configurations .............................................200
References .......................................................................201
12 Properties of NanostructuredMaterials ....................................203
12.1 Theory of Nanostructures ..............................................203
12.2 Thermal Conduction in Low-DimensionalMaterials .................208
12.3 Observations on Nanostructures .......................................213
12.4 Preparation of Nanostructures .........................................216
References .......................................................................219
13 Thermionic Energy Conversion..............................................221
13.1 Vacuum Thermoelements ..............................................221
13.2 Thermionic Emission in Solids ........................................228
References .......................................................................233
Bibliography ........................................................................235
Index .................................................................................237
Index of Elements, Compounds and Alloys .....................................241补充信息:
出版社:Springer
Springer Series in Material Science ISSN 0933-033X
ISBN 978-3-642-00715-6 e-ISBN 978-3-642-00716-3
DOI 10.1007/978-3-642-00716-3
Springer Heidelberg Dordrecht London New York
Library of Congress Control Number: 2009929170
页数:250页

[ Last edited by 穿越千年 on 2015-12-2 at 02:48 ]
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引用回帖:
119楼: Originally posted by shtrish at 2015-04-27 16:36:13
楼主逆天啊,总是有好资料

我这还有很多珍藏版的,没有时间上传,这些书够热电工作者看很长时间。
120楼2015-04-27 20:24:44
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从事热电材料的虫友们,这本书非常的不错,之前求这本书的人也很多,怎么不见下载的。
2楼2013-06-25 11:10:27
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ted1277

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★★★★★ 五星级,优秀推荐

哇~谢谢啦
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顶个屁,骗人的,不能下载!
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45楼: Originally posted by peterflyer at 2013-08-16 00:24:24
顶个屁,骗人的,不能下载!

怎么不能下载了啊?怎么提示的。我自己再下一次也没出现问题
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45楼: Originally posted by peterflyer at 2013-08-16 00:24:24
顶个屁,骗人的,不能下载!

我又试了一下,还真出现了问题,谢谢提醒,我再找找原因!
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45楼: Originally posted by peterflyer at 2013-08-16 00:24:24
顶个屁,骗人的,不能下载!

现在可以了,之前已经有100多次下载了,应该不是一开始就出现了问题,最开始的时候我自己都下载试过了,我也不知道后来出现了什么情况。
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