| 查看: 144 | 回复: 2 | |||
| 当前主题已经存档。 | |||
tcmtang2001木虫 (正式写手)
|
[交流]
一篇关于催化羰基化的好东东与大家分享
|
||
|
一篇不错的文献综述哈 关于羰基化催化剂的有关问题综述的很全面有借鉴意义哈 Progress in hydroformylation and carbonylation Abstract The last 15 years of hydroformylation and carbonylation chemistry are reviewed, including technical and commercial aspects. Keywords: Carbonylation; Hydroformylation; Homogeneous catalysis; Organometallic complexes 1. Introduction ................................................................................................................................ 2. Hydroformylation .......................................................................................................................... 2.1. Catalysts ............................................................................................................................... 2.l.l.Variationofthecentralatom .................................................................................................. 2.1.1.1. Monometallic catalysts ............................................................................................... 2.1.1.2. “Poly”metallic catalysts ............................................................................................. 2.1.2. Variation of the ligand ......................................................................................................... 2.1.2.1. Basic principles ....................................................................................................... 2.1.2.2. Phosphites ............................................................................................................ 2.1.2.3. Phosphines ............................................................................................................ 2.1.2.4. Water-soluble phosphines ............................................................................................ 2.1.2.5. Deactivation mechanism of rhodium-phosphine catalysts ........................................................... 2.1.3. Variation of the application phase ............................................................................................. 2.1.3.1. General ............................................................................................................... 2.1.3.2. Aqueous catalysts ..................................................................................................... 2.1.3.3. Other biphasic catalysts .............................................................................................. 2.1.3.3.1. Non-aqueous systems ...................................................................................... 2.1.3.3.2. Anchoredcatalysts ........................................................................................ 2.1.3.3.2.1. Polymer-supported catalysts .................................................................. 2.1.3.3.2.2. SLPC ......................................................................................... 2.1.3.3.2.3. SAPC ......................................................................................... 2.2.Specialapplicationsofhydroformylation ............................................................................................. 2.2.1. Special olefins .................................................................................................................. 2.2.2. Asymmetric hydroformylation ................................................................................................. 2.3.Specialvariantsofhydroformylation ................................................................................................. 2.3.1. Aminomethylation ............................................................................................................. 2.3.2. Homologation of carboxylic acids ............................................................................................. 2.3.3. Miscellaneous reactions ........................................................................................................ 2.4. Technical developments in hydroformylation ........................................................................................ 2.4.1. General remarks ................................................................................................................ 2.4.2. Today’s 0x0 processes ......................................................................................................... 2.4.2.1. UCC process .......................................................................................................... 2.4.2.2. Ruhrchemie/Rhne Poulenc (RCH/RP) process ..................................................................... 2.4.2.3. BASF process ......................................................................................................... 2.4.2.4. Exxon process ........................................................................................................ 2.4.2.5. Other processes ....................................................................................................... 2.4.3. Special developments .......................................................................................................... 2.4.4. Future aspects .................................................................................................................. 3. Carbonylation ............................................................................................................................... 3.1. New developments .................................................................................................................... 3.1.1. Carbonylation of olefins ...... ............................................................................................... 3.1.1.1. Hydrocarboxylations and related reactions ........................................................................... 3.1.1.2. Oligomerizations and polymerizations with CO ..................................................................... 3.1.1.3. Oxidative carbonylations ............................................................................................. 3.1.2. Carbonylation of alkynes ........... .......................................................................................... 3.1.2.1. Hydrocarboxylations and related reactions ........................................................................... 3.1.2.2. Others ................................................................................................................. 3.1.3. Carbonylation of CX-compounds .............................................................................................. 3.1.3.1.Reactionsofat-y1-andvinyl-X ....................................................................................... 3.1.3.2. Reactions of alkyl-X .................................................................................................. 3.1.3.3. Reactionsofbenzyl-andallyl-X ..................................................................................... 3.1.4. Carbonylation of aldehydes .................................................................................................... 3.1.5. Amidocarbonylation ........................................................................................................... 3.1.6. Carbonylation of nitrogen derivatives ......................................................................................... 3.1.7. Other carbonylations ........................................................................................................... 3.2. Technical developments ............................................................................................................... 4. Outlook .................................................................................................................................... References .................................................................................................................................... [ Last edited by nxl5096224 on 2007-10-5 at 11:45 ] |
回复此楼» 猜你喜欢
大连海事大学国家级人才团队（船舶洁净能源研究中心）2027年博士研究生招生启事
已经有1人回复
-
中国地质大学杨明教授组招收2027年博士能源化学、催化材料方向（每月5K+）
已经有56人回复
-
化学工程及工业化学论文润色/翻译怎么收费?
已经有228人回复
-
中国地质大学杨明教授组招收2027年博士能源化学、催化材料方向（每月5K+）
已经有58人回复
-
东南大学杰青团队-催化方向硕博士生、博士后、科研助理招募
已经有0人回复
-
北京工业大学_能源催化（能源环境协同催化）_方向拟招收2027年学术和专业学位博士生
已经有2人回复
-
上海华东理工大学2027年海内外人才招聘
已经有1人回复
tcmtang2001
木虫 (正式写手)
- 应助: 0 (幼儿园)
- 金币: 3439.2
- 散金: 4
- 红花: 2
- 帖子: 381
- 在线: 63.4小时
- 虫号: 266798
- 注册: 2006-07-22
- 性别: GG
- 专业: 催化化学
2楼2007-10-03 22:45:22
