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hxd123

新虫 (小有名气)

[求助] 绝对构型的确定

近期投一个晶体的文章,审稿人回复的见如下:
I realize that you determined the absolute structure from the value of the Flack parameter, but my request was that you include a comment on how you were able to obtain a meaningful value for the Flack parameter in your case (in most instances where there are no heavy atoms to provide anomalous dispersion effects (and thus provide a means to determine an absolute structure by the Flack parameter) the Flack parameter cannot be determined with certainty). Is your low value for the Flack parameter just a coincidence or is there some feature of your data that enabled you to obtain a reliable value?

大概意思是怎么确定的绝对构型,我的分子力没有重原子,只有CHON,问打单晶的老师,说是用铜板做的,偏差是0.01(15),我还需要怎么解释呢,需要再加一些什么参数呢?对此一点都不懂啊,求大神赐教啊~~~~
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wfgd

木虫 (小有名气)

【答案】应助回帖

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hxd123: 金币+10, ★★★★★最佳答案 2013-03-11 09:09:48
关于这方面的问题,之前有他人已详细介绍过http://muchong.com/bbs/viewthread.php?tid=1379918
2楼2013-03-10 17:56:28
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