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有机小分子外文翻译成中文
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Significant advances in our understanding of how these enzymes function have accrued, in part from the high-resolution structures of resting states and reactive metalloenzyme intermediates through X-ray crystallography and spectroscopic characterization, and from detailed mechanistic information from intertwined kinetics, synthetic modelling and theoretical investigations. Such studies have produced candidates for the active oxidants in several classes of important copper and iron enzymes that are the subject of this review. These findings have fuelled the debate about the mechanisms by which these enzymes operate; one common issue being whether O–O bond cleavage occurs before, during or after attack on the organic substrate. |
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hookhans
铁杆木虫 (著名写手)
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莫莫1230(phu_grassman代发): 金币+5, 翻译EPI+1, good job 2013-04-06 21:14:07
莫莫1230(phu_grassman代发): 金币+5, 翻译EPI+1, good job 2013-04-06 21:14:07
| 我们在理解这些酶如何作用方面取得了显著的进步。这些认识一部分来自由X-射线晶体衍射和光谱表征得到的静态和反应的金属络合酶中间体高分辨率结构，一部分来自交织动力学、合成模型建立和理论研究提供的详细的机理信息。本文就是针对在这样的研究下衍生出的几类重要的铜基、铁基酶中活性氧化剂的代表进行综述。 这些发现激发了这些酶作用机理的讨论， 即一个人们共同关系的议题：O–O键的裂解是发生攻击有机底物之前，期间，还是之后？ |
4楼2013-03-09 11:30:33