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影响自组装过程的各种因素小结
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超分子自组装除了受金属和配体自身的性质影响外，害兽各种外界的物理和化学因素的影响，如溶剂、模板、反应温度、反应物的配比、抗衡离子、溶剂、pH值等等，他们单独或联合在自组装过程中其作用，从而导致了结构各异、性能奇特的超分子聚集体。现将他们分类，以便与虫友们分享。有些文献，你可以进行文献追踪，以便查到更多的资源。我暂先提供这些，希望大家多多灌水，充实这一部分内容。 1。阳离子引导自组装： 1）Title: A novel ribbon-candy-like supramolecular architecture of cadmium(II)-terephthalate polymer with giant rhombic channels: twofold interpenetration of the 3D 8(2)10-a net Author(s): Dai JC, Wu XT, Fu ZY, Hu SM, Du WX, Cui CP, Wu LM, Zhang HH, Sun RQ Source: CHEMICAL COMMUNICATIONS (1): 12-13 2002 。 2）Title: Metal-directed self-assembly: Two new metal-binicotinate grid polymeric networks and their fluorescence emission tuned by ligand configuration Author(s): Wu BL, Yuan DQ, Jiang FL, Wang RH, Han L, Zhou YF, Hong MC Source: EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (13): 2695-2700 JUL 5 2004 2. 阴离子引导自组装： 1）Title: Anion-directed assembly of macrocycle and helix Author(s): Zhang XJ, Zhou XP, Li D Source: CRYSTAL GROWTH & DESIGN 6 (6): 1440-1444 JUN 2006 2） Title: Anion-templated synthesis Author(s): Vilar R Source: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 42 (13): 1460-1477 2003 3）Title: Structural diversity of silver(I) 4,6-dipyridyl-2-aminopyrimidine complexes: Effect of counteranions and ligand isomerism Author(s): Chi YN (Chi, Ying-Nan), Huang KL (Huang, Kun-Lin), Cui FY (Cui, Feng-Yun), Xu YQ (Xu, Yan-Qing), Hu CW (Hu, Chang-Wen) Source: INORGANIC CHEMISTRY 45 (26): 10605-10612 DEC 25 2006 4） Title: Anion effect on the structural conformation of tetranuclear cadmium(II) complexes Author(s): Wang RH, Yuan DQ, Jiang FL, Han L, Gong YQ, Hong MC Source: CRYSTAL GROWTH & DESIGN 6 (6): 1351-1360 JUN 2006 3。 溶剂效应： 1） Title: Solvent-tuned azido-bridged Co2+ layers: Square, honeycomb, and Kagome Author(s): Wang XY, Wang L, Wang ZM, Gao S Source: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 128 (3): 674-675 JAN 25 2006 2） Title: Solvent-directed layered Co(II) coordination polymers with unusual solid-state properties: from a nanoporous framework to the dense polythreading 3-D aggregation Author(s): Du M (Du, Miao), Wang XG (Wang, Xiu-Guang), Zhang ZH (Zhang, Zhi-Hui), Tang LF (Tang, Liang-Fu), Zhao XJ (Zhao, Xiao-Jun) Source: CRYSTENGCOMM 8 (11): 788-793 2006 4。 温度的影响： 1）Title: Three-dimensional eight- or four-connected metal-organic frameworks tuned by hydrothermal temperatures Author(s): Liu CM (Liu, Cai-Ming), Gao S (Gao, Song), Zhang DQ (Zhang, De-Qing), Zhu DB (Zhu, Dao-Ben) Source: CRYSTAL GROWTH & DESIGN 7 (7): 1312-1317 JUL 2007 2） Title: The role of temperature in the synthesis of hybrid inorganic-organic materials: the example of cobalt succinates Author(s): Forster PM, Burbank AR, Livage C, Ferey G, Cheetham AK Source: CHEMICAL COMMUNICATIONS (4): 368-369 FEB 21 2004 5。pH值： 1）Title: pH-dependent assembly of Keggin-based supramolecular architecture Author(s): Zheng PQ, Ren YP, Long LS, Huang RB, Zheng LS Source: INORGANIC CHEMISTRY 44 (5): 1190-1192 MAR 7 2005 2）Title: Construction of a three-fold parallel interpenetration network and bilayer structure based on copper(II) and trimesic acid Author(s): Chen WX (Chen, Wen-Xian), Wu ST (Wu, Shu-Ting), Long LS (Long, La-Sheng), Huang RB (Huang, Rong-Bin), Zheng LS (Zheng, Lan-Sun) Source: CRYSTAL GROWTH & DESIGN 7 (6): 1171-1175 JUN 2007 |
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