24小时热门版块排行榜    

查看: 496  |  回复: 0

11900490

木虫 (知名作家)

[交流] 三价金的晶体结构

http://onlinelibrary.wiley.com/doi/10.1002/anie.201209140/full


三价金的晶体结构

图片1.png

Angewandte Chemie International Edition Volume 52, Issue 6, pages 1660-1663, 2 JAN 2013 DOI: 10.1002/anie.201209140 http://onlinelibrary.wiley.com/d ... 201209140/full#fig1



A Missing Gold Link: An AuIII alkene complex has been prepared and characterized by NMR spectroscopy and X-ray crystallography. Its bonding features have been analyzed by DFT calculations and natural bond orbital (NBO) analysis. In [(cod)AuMe2]+, the unequal AuC bond lengths result from the domination of the preference of 1,5-cyclooctadiene (cod) for nonparallel double bonds over back donation from the metal which favors parallel double bonds.

ncontent.gif



[ Last edited by 11900490 on 2013-2-4 at 11:58 ]
回复此楼
已阅   回复此楼   关注TA 给TA发消息 送TA红花 TA的回帖

智能机器人

Robot (super robot)

我们都爱小木虫

相关版块跳转 我要订阅楼主 11900490 的主题更新
普通表情 高级回复 (可上传附件)
信息提示
请填处理意见