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shawpion

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[½»Á÷] ÊÕµ½ Journal of Biotechnology and Bioinformatics Éó¸åÐÅ£¬ÊÇÔõô»ØÊÂÄØ£¿ ÒÑÓÐ2È˲ÎÓë

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Basic Research Journal of Biotechnology and Bioinformatics
www.basicresearchjournals.org

Basic Research Journal of Biotechnology and Bioinformatics

Dear Colleague,

A manuscript titled ?Antimicrobial activity of unexpected cyclopalladate complexes resulted from cyclopalladation of schiff base derived from cinnamaldehyde with 2-amino phenol? was received by us for publication.  We will be highly obliged if you could find time to review the manuscript. Please find the abstract below:

ABSTRACT

Reaction of equimolar amounts of Pd(OAc)2 with Schiff base ligand (C6H5CH=CH?CH=N?C6H4?2OH)(L) gave the dimmeric acetato bridged cyclopalladate complex(1) with folded open book shape structure, when the ligand was acted as bidentate through activated aliphatic carbon atom and azomethen nitrogen atom. This is unexpected result while the expected result is that the ligand acts as tridentate ligand through activated aliphatic carbon atom, azomethine nitrogen atom and hydroxyl oxygen atom. Complex(1) was treated with NaCl, NaBr and NaI and gave the corresponding halido bridged complexes(2), (3) and (4), respectively with unfolded planar structure. The reaction of complex(2) with pyridine and complex(3) with triphenyl phosphine gave the monomeric complexes (5) and (6), respectively. All the newly synthesized compounds were characterized via microanalytical data and spectral tools (IR, electronic, Mass and 1HNMR) spectroscopy. The ligand and the complexes were tested as antimicrobial agents and showed high activity as antibacterial and antifungal agents. Also the minimum inhibitor concentrations (MIC) of the new compounds were determined by serial dilution method.

Keywords: Cyclopalladate complexes, Spectroscopy, Antimicrobial activity, MIC.

Kindly email us to acknowledge the reception of this mail and I will be most grateful to hear from you.

Best regards,

Owhofasa O Gabriel
Editorial Assistant,
Basic Research Journal of Biotechnology and Bioinformatics (BRJBB)
E-mail: jbb@basicresearchjournals.org
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