| 查看: 480 | 回复: 0 | ||
[求助]
求助NMR高手帮翻译几个单词及短句
|
|
就是下面带红色的单词或短句，有些拿不准什么意思，把整句列出来是为了显示整个语境，请高手指点下，不会花许多时间的。 1. Each nuclide has 2I+ 1 energy levels, characterized by a quantum number m, with values I, I −1, I −2, . . . , −I. In absence of the magnetic field, these energy levels have the same energy (they are degenerate), but the degeneracy lift under a magnetic field interaction between them and the field. 2. One of the main problems in obtaining the NMR spectra of solids is that there are a number of phenomena inducing a range of magnetic field strengths at individual nuclei of the same nuclide in a sample, which causes broad peaks. These phenomena include (a) interaction of dipole moments of individual nuclei (dipole-dipole interaction), (b) anisotropy of the electronic shielding at individual sites (chemical shift anisotropy), and (c) interaction of the quadrupole moment of a nuclide with I ≥ 1 with the electric field gradient at the nucleus 3.Quadrupole effects cause peak broadening, displacement of the peak from the isotropic (true) chemical shift, and distortion of the peak shape. 移动？？ 4. In general, the following properties of the MAS spectra could be defined:…… (d) increasing inhomogeneous broadening （增加不均匀加宽？）reduces the sharpness of the singularity. （锐度？？） 5. Under MAS conditions, the peak is narrowed about a factor of 3, the isotropic chemical shift is at the left edge （左边缘？？）of the peak, and the center of gravity is displaced （转移？？）to the right of the isotropic chemical shift. 6. As （因为？当……时）the NMR frequencies are all in the radio frequency range, NMR spectrometers are computer operated radio （无线电？射电？还是应该翻译成电磁波？）transmitting and receiving systems controlled by a computer. 7. The attainable spinning speed depends on the gas pressure and the uniformity （均匀度？？）of the sample packing in the rotor. 8. After these pulses, the sample begins to emit a radio frequency signal at a resonance frequency as the spin system （旋转系统？？自旋系统？？）dephases (t2 relaxation time). 9. A difficulty in using NMR spectroscopy, especially for many natural samples, is that paramagnetic components or impurities (most commonly Fe or Mn) cause an extensive peak broadening. This broadening is due to a range of（一系列？？） chemical shifts caused by magnetic field non-homogeneity due to the interaction of unpaired d- or f-electrons within the applied magnetic field. 10. In the high-temperature spectra, where the solvent as well as the dissolved investigated substance are solely ionic in character, an extremely fast mutual exchange of nuclei takes place. 11. The reported 19F spectra were corrected for a broad probe-head signal due to the presence of Teflon in the probe assembly. 12. Their 27Al chemical shifts range between −13 and −1.4 ppm and are typically more shielded than the AlO6 octahedrons in oxide compounds. 13. Magnetically active samples using the NMR determinable atomic nuclei are only those, having a nonzero atomic spin. |
回复此楼» 猜你喜欢
基金未中，这种答复是模板吗？
已经有5人回复
-
为什么资助数各大高校都创新高，自己申请怎么就这么难
已经有5人回复
-
有多少人是今天查系统知道结果的？
已经有17人回复
-
导师吐槽：我怎么摊上了这么个极品研究生！
已经有5人回复
-
怎么看青基中了没有啊
已经有5人回复
-
梦想
已经有3人回复
-
面上合作单位盖章
已经有3人回复
-
看板上这么多中的，有点像50人群里49个人都是骗子的那种感觉……
已经有5人回复
-
基金不中，共勉
已经有7人回复
-
为什么 国际(地区)合作与交流项目 没有放榜？
已经有11人回复
找到一些相关的精华帖子，希望有用哦~
800个有趣句子帮你记忆7000个单词（完整修正版
已经有207人回复
- 2013考研通过句子记忆英语词汇、写作翻译要点词组归纳
已经有73人回复
- 翻译一句话,单词有注释，就是句子结构不太会安排
已经有5人回复
- 一些英语资源：恋爱中采用的句子，名言名句，chinese易犯的句子、词汇等等
已经有20人回复
- 【分享】800个有趣句子帮你记忆7000个单词(完整修正版)【已搜索无重复】
已经有1391人回复
- 【分享】100个句子记完的7000单词，俞敏洪的杰作【已搜索无重复】
已经有31人回复
- 求助句子中单词翻译
已经有3人回复
- 求助，句子中的某些单词的特殊用法
已经有10人回复
- 【资源】俞敏洪：100个句子记完的7000单词
已经有42人回复
- 【资源】一些有趣的句子 帮你记住单词
已经有10人回复
- 俞敏洪说：背完这100个句子，你已经背过7000个单词！！!
已经有1129人回复
点击这里搜索更多相关资源科研从小木虫开始，人人为我，我为人人
投票:
