之前看过一篇文献,也是类似的内容,当然,材料是不一样的,如下图:
很微小的差异,文中所述:...the -OH stretching vibrations at 3420 cm-1 also shifted to higher frequencies. The result indicated that the surface M-OH was active site and the quantitative substitution of the M-OH groups by F- played a key role in F- adsorption.
只用IR基本也能说明问题,文献是Journal of Hazardous Materials
1.jpg