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1. Introduction Palygorskite (PAL) is a sort of natural nano-scale layer-ribbon hydrated magnesium aluminum silicate mineral. PAL exhibits particular rod-like crystal microstructure with the length of 1¨C5 ¦Ìm and diameter of 20¨C100 nm. The special rod-like geometry generates numerous nanopores parallel to the crystal rods, which endows PAL with moderate cation exchange capacity, pore structure, large specific surface area and adsorption properties. Thus, PAL has been widely used in various fields including heavy metal ions and dyes adsorbent, catalyst support, drug carrier, inorganic crosslinker as well as reinforcement filler of polymer materials [1¨C8]. However, the rod-like crystals of raw PAL prefer to aggregate as crystal bundles or aggregates [9], which do not exhibit the nanometer characteristics. Thus far, chemical modification and physical approaches have been employed to dissociate and disperse crystal bundles of PAL for improving its physical¨Cchemical properties and extending its application fields such as adsorbents and functional materials, etc. [10¨C12]. Among these methods, physical approaches such as highshear mixing, extrusion, grinding and ultrasonication [13¨C15] were1. Introduction Palygorskite (PAL) is a sort of natural nano-scale layer-ribbon hydrated magnesium aluminum silicate mineral. PAL exhibits particular rod-like crystal microstructure with the length of 1¨C5 ¦Ìm and diameter of 20¨C100 nm. The special rod-like geometry generates numerous nanopores parallel to the crystal rods, which endows PAL with moderate cation exchange capacity, pore structure, large specific surface area and adsorption properties. Thus, PAL has been widely used in various fields including heavy metal ions and dyes adsorbent, catalyst support, drug carrier, inorganic crosslinker as well as reinforcement filler of polymer materials [1¨C8]. However, the rod-like crystals of raw PAL prefer to aggregate as crystal bundles or aggregates [9], which do not exhibit the nanometer characteristics. Thus far, chemical modification and physical approaches have been employed to dissociate and disperse crystal bundles of PAL for improving its physical¨Cchemical properties and extending its application fields such as adsorbents and functional materials, etc. [10¨C12]. Among these methods, physical approaches such as highshear mixing, extrusion, grinding and ultrasonication [13¨C15] were1. Introduction Palygorskite (PAL) is a sort of natural nano-scale layer-ribbon hydrated magnesium aluminum silicate mineral. PAL exhibits particular rod-like crystal microstructure with the length of 1¨C5 ¦Ìm and diameter of 20¨C100 nm. The special rod-like geometry generates numerous nanopores parallel to the crystal rods, which endows PAL with moderate cation exchange capacity, pore structure, large specific surface area and adsorption properties. Thus, PAL has been widely used in various fields including heavy metal ions and dyes adsorbent, catalyst support, drug carrier, inorganic crosslinker as well as reinforcement filler of polymer materials [1¨C8]. However, the rod-like crystals of raw PAL prefer to aggregate as crystal bundles or aggregates [9], which do not exhibit the nanometer characteristics. Thus far, chemical modification and physical approaches have been employed to dissociate and disperse crystal bundles of PAL for improving its physical¨Cchemical properties and extending its application fields such as adsorbents and functional materials, etc. [10¨C12]. |
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Ðí°²: ½ð±Ò+5, ·ÒëEPI+1, ¡ïÓаïÖú 2012-10-21 19:50:55
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1. Introduction Palygorskite (PAL) is a sort of natural nano-scale layer-ribbon hydrated magnesium aluminum silicate mineral. PAL exhibits particular rod-like crystal microstructure with the length of 1¨C5 ¦Ìm and diameter of 20¨C100 nm. The special rod-like geometry generates numerous nanopores parallel to the crystal rods, which endows PAL with moderate cation exchange capacity, pore structure, large specific surface area and adsorption properties. Thus, PAL has been widely used in various fields including heavy metal ions and dyes adsorbent, catalyst support, drug carrier, inorganic crosslinker as well as reinforcement filler of polymer materials [1¨C8]. PALÊÇÒ»ÖÖ²ã´ø×´µÄÌìÈ»ÄÉÃ×Ë®ºÏ¹èËáþÂÁ¿óÎïÖÊ¡£Ëü¾ßÓÐÌØÊâµÄ°ô×´½á¾§Î¢½á¹¹£¬³¤1¨C5 ¦Ìm£¬Ö±¾¶ 20¨C100 nm¡£°ô×´¼¸ºÎ½á¹¹Äܹ»²úÉú´óÁ¿Æ½ÐÐÓÚ¾§Ìå°ôµÄÄÉÃ׿ף¬ÕâʹµÃPAL¾ßÓÐÊÊÖеÄÑôÀë×Ó½»»»ÈÝÁ¿¡¢¿×½á¹¹¡¢½Ï´óµÄ±È±íÃæ»ý¡¢Îü¸½ÐÔÄÜ¡£Òò´Ë£¬PALºÍ¾ÛºÏÎïÔöÇ¿ÐÍÌîÁÏÒ»Ñù£¬±»¹ã·ºÓÃÓÚÖØ½ðÊôÀë×ÓÎü¸½¼Á¡¢È¾ÁÏÎü¸½¼Á¡¢´ß»¯¼ÁÔØÌå¡¢Ò©ÎïÔØÌå¡¢ÎÞ»ú½»Áª¼Á¡£ [1¨C8]. |
2Â¥2012-10-20 13:51:15
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°®ÓëÓêÏÂ: ½ð±Ò+1, ¸ÐлӦÖú 2012-10-20 17:06:29
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°®ÓëÓêÏÂ: ½ð±Ò+1, ¸ÐлӦÖú 2012-10-20 17:06:29
Ðí°²: ½ð±Ò+5, ¡ïÓаïÖú 2012-10-21 19:51:04
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