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As suggested by Referee 1, "the authors should discuss the observed results further by comparing with established imidazolium ionic liquid surfactants and Gemini imidazolium ionic liquid surfactants and by commenting potential advantages of the reported two-tail versions". The revised manuscript involves mostly format modification. To address the above comment, the authors revised the conclusion that "We found that these surfactants were more surface active than Gemini imidazolium ionic liquid surfactants[15], However, this conclusion still need further experiment research to prove and we will pay more attention to the latest progress in this field". Such statement is inappropriate; if experiments need to be done, then do it and show the data.

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As suggested by reviewer 1, the authors should discuss the observed results further by comparing with established imidazolium ionic liquid surfactants and Gemini imidazolium ionic liquid surfactants and by commenting potential advantages of the reported two-tail versions. However, the authors respond only in the conclusion section that they found the established two-tail surfactants had higher surface activity than Gemini imidazolium ionic liquid surfactants (See ref.15). The authors did not give out further experimental evidences about why the special structures of those ionic liquid surfactants have significant impact on their surface activity. In addition, no corresponding discusses on the influences from the configuration changes of those imidazolium ionic liquid surfactant molecules in micellization processes on the enthalpy-entropy compensation phenomenon.
The reviewer 2 suggested the authors should include in the introduction and conclusion section a clear scientific justification how the works contribute to new fundamental understanding in the specific area of research. However, the authors does not respond that requirements appropriately. In my opinion, it is definitely important for the audients to understand the originality of the present works.
In experimental section 2.3, about the determining the solution surface tension by drop volume method, please give out the detailed instructions on the experimental equipments, and the corresponding parameters and procedures for measurement of the surface tensions. As such, the audients can test the accuracy of the experimental data and whether the conclusions are acceptable.
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