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3Â¥2012-07-28 19:22:30
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dxw7610: ½ð±Ò+5, ¡ïÓаïÖú 2012-07-31 11:33:39
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Fresh rust that stripped off presents dark color mixed with red and light green, and the light green disappears once exposed in air.   2) Ñô¼«ÇøÊͷŵĵç×Óͨ¹ý¸Ö½îÁ÷ÏòÒõ¼«Çø£¬Í¬Ê±Éú³ÉFe2+Ó븽½üµÄCl-Àë×Ó½áºÏÉú³ÉÒ×ÈܵÄÖмäÏàÌú-ÂÈÂçºÏÎï£¬Ëæºó´Ó¸Ö½îÑô¼«ÇøÏò»ìÄýÍÁ¿×Ï¶Ç¨ÒÆ£¬·Ö½âΪºÖÉ«µÄFe(OH)2£¬²¢³ÁµíÔÚÑô¼«ÇøÖÜΧ£¬Í¬Ê±·Å³öH+ºÍCl-£¬ËüÃÇÓֻص½Ñô¼«Çø£¬Ê¹Ñô¼«Çø¸½½ü¿×϶Һ¾Ö²¿Ëữ£¬Cl-ÔÙ´ø³ö¸ü¶àµÄFe2+£¬ÕâÑùCl-¼ÓËÙ¸Ö½îÐâÊ´¡£Electrons released from the positive column flow to the negative column through the steel bar, and Fe2+ created in positive column and the Cl- nearby combine together which produces diffluent Iron chlorine complex in intermediate phase. Then the complex drifts toward the holes of the concrete from the positive column in the steel bar, and it decomposes to Fe(OH)2 in brown, which is separated around  the positive column and releases H+ and Cl+ at the same time. After then, the H+ and Cl- come back and Local acidification occurs around the pore fluid, which attribute to the increase of the Fe2+ brought by Cl-. Thus Cl- accelerate the corrosion of the steel bar.
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2Â¥2012-07-28 19:19:59
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dxw7610: ½ð±Ò+10, ·­ÒëEPI+1, ¡ï¡ï¡ïºÜÓаïÖú 2012-07-31 11:33:07
1) The color of fresh rust just stripped off is black mingled with red and light green which would fade away after exposed to air.
2) Anode region discharge electrons which flow through steel bar into cathod space, and produce Fe2+ simultaneously. Fe2+  then combine with nearby Cl- ion, forming intermediate phase ferrum-cholorine complex. After that, the complex migrate from steel bar anode region to the void space in concrete where it decompose into brown Fe(OH)2 which precipitate around the anode region. The H+ and Cl- ions released by aforementioned process then must come back into the anode region, acidizing the aqueous solution in the void space near anode region. The Cl- ion then would  bring out more Fe2+ ion over and over again in this way, that would accelerate the corrosion process of the reinforcing steel bar.
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4Â¥2012-07-29 20:18:11
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