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【答案】应助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ Mally89: 金币+1 2012-05-17 13:49:10 转弯为你相遇: 金币+20, 翻译EPI+1, ★有帮助 2012-05-21 07:29:50 sltmac: 金币+20 2012-05-21 16:41:16
Abstract: 2, 3, 5 - trichloropyridine is a kind of important intermediates of pesticides, it commonly used in the development of various herbicides.3, 5 - dichloro - 2 - arylpyridine compound is one kind of them.In this paper ,we used 2, 3, 5 - trichloro pyridine and aryl boric acid as raw materials, synthesized a number of uncommon 3, 5 - dichloro - 2 - aryl pyridine compounds by Suzuki coupling reactio in aqueous catalyzed by palladium.This process produces less the three wastes, under mild conditions and have a high yield.we characterized raw materials and target product by 1H NMR and mass spectrometry , and determined the structure of target product .
Keywords: 2, 3, 5 - trichloro pyridine boric acid; aryl boric acid ; Suzuki coupling reaction catalyzed by palladium; synthesis;; 3, 5 - dichloro - 2 - aryl pyridine compounds;
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