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11900490

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[交流] 晶体的应用--研究“亚稳态光照反应” 已有2人参与

Paul Raithby is Professor of Inorganic Chemistry at the University of Bath, UK, prior to which he was a faculty member of the Department of Chemistry and Fellow of St Catharine's College at the University of Cambridge for 25 years. A past president of the British Crystallographic Association (2006–2009), he has been awarded the RSC Corday Morgan Medal and Prize (1988) and the RSC Prize for Structural Chemistry (2008). He has over 770 publications and is among the 30 most cited British physical scientists. His research interests span aspects of chemical crystallography, organometallic polymer synthesis and investigations into their opto-electronic properties, transition metal carbonyl cluster chemistry, and investigations of structural systematics using statistical and molecular mechanics methodologies.
Paul Raithby

(a) Ground state structure of 1. (b) Photo-activated structure 1# showing the remaining ground state and 16% component of the metastable nitrito form. (c) Close-up of the NO2 group in 1#, separated into the two components and confirming the presence of the endo-nitrito form. Where shown displacement ellipsoids are plotted on 30% probability and hydrogen atoms and the disorder of the ethylene chain are eliminated for clarity.

Solid state Raman spectrum of 1 after 4 h UV LED photolysis warmed from 100 K (black) to 110 K (red), 120 K (green) and 130 K (blue).

[ Last edited by 11900490 on 2012-3-17 at 19:30 ]

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