| 查看: 9480 | 回复: 270 | |||||||||||||||||||||
| 【奖励】 本帖被评价228次，作者战国时代增加金币 180.2 个 | |||||||||||||||||||||
| 本帖产生 1 个 ECEPI ，点击这里进行查看 | |||||||||||||||||||||
| 当前只显示满足指定条件的回帖，点击这里查看本话题的所有回帖 | |||||||||||||||||||||
[资源]
【电化学基础书籍】electrochemistry in nonaqueous solutions
|
|||||||||||||||||||||
|
Kosuke Izutsu (writer) Electrochemistry inNonaqueous Solutions A majority of chemical reactions are carried out in solution. The use of a solvent as reaction medium makes it easy to control reaction conditions such as tempera- ture, pressure, pH, rate of mass transfer, and concentration of reactant. Water is the most popular solvent. However, by using appropriate non-aqueous solvents, substances that are insoluble in water can be dissolved, substances that are un- stable in water remain stable, and chemical reactions that are impossible in water become possible. The reaction environments are markedly wider in non-aqueous solvents than in water. The widespread use of non-aqueous solvents, especially dipolar aprotic solvents, began in the 1950s in various fields of pure and applied chemistry and has con- tributed greatly to later advances in chemical sciences and technologies. From the very beginning, electrochemistry in non-aqueous solutions has played an impor- tant role in exploring new chemical possibilities as well as in providing the meth- ods to evaluate static solvent effects on various chemical processes. Moreover, many new electrochemical technologies have been developed using non-aqueous solvents. Recently, electrochemistry in non-aqueous solutions has made enormous progress: the dynamic solvent effects on electrochemical processes have been greatly elucidated and solvent effects are now understood much better than be- fore. On the other hand, however, it is also true that some useful solvents have properties that are problematic to human health and the environment. Today, ef- forts are being made, under the framework of ‘green chemistry’, to find environ- mentally benign media for chemical processes, including harmless non-aqueous solvents, immobilized solvents, ionic liquids, supercritical fluids, aqueous sys- tems, and even solventless reaction systems. For electrochemical purposes, replac- ing hazardous solvents by harmless solvents, ionic liquids and supercritical fluids appears to be promising. This book was written to provide readers with some knowledge of electrochem- istry in non-aqueous solutions, from its fundamentals to the latest developments, including the current situation concerning hazardous solvents. The book is di- vided into two parts. Part I (Chapters 1 to 4) contains a discussion of solvent prop- erties and then deals with solvent effects on chemical processes such as ion solva- tion, ion complexation, electrolyte dissociation, acid-base reactions and redox reac- tions. Such solvent effects are of fundamental importance in understanding chem- istry in non-aqueous solutions; furthermore, their quantitative evaluations are of- ten carried out by means of electrochemical techniques. Part II (Chapters 5 to 12) mainly deals with the use of electrochemical techniques in non-aqueous solu- tions. In Chapter 5, the fundamentals of various electrochemical techniques are outlined in preparation for the following chapters. In Chapters 6 to 9, the applica- tions of potentiometry, conductimetry, polarography, voltammetry, and other new electrochemical techniques in non-aqueous solutions are discussed by focusing on the chemical information they provide. Chapters 10 and 11 examine methods of selecting and purifying the solvents and electrolytes of electrochemical impor- tance. Finally, in Chapter 12, some practical applications of non-aqueous solvents in modern electrochemical technologies are discussed. These include their use in batteries, capacitors and display devices, and such processes as electrolytic refin- ing, plating, synthesis and polymerization. The applicability of ionic liquids and supercritical fluids as environmentally benign media for electrochemical technol- ogy is also dealt with. Most chemists are familiar with chemistry in aqueous solutions. However, the common sense in aqueous solutions is not always valid in non-aqueous solutions. This is also true for electrochemical measurements. Thus, in this book, special emphasis is placed on showing which aspects of chemistry in non-aqueous solu- tions are different from chemistry in aqueous solutions. Emphasis is also placed on showing the differences between electrochemical measurements in non-aque- ous systems and those in aqueous systems. The importance of electrochemistry in non-aqueous solutions is now widely recognized by non-electrochemical scientists – for example, organic and inorganic chemists often use cyclic voltammetry in aprotic solvents in order to determine redox properties, electronic states, and reac- tivities of electroactive species, including unstable intermediates. This book will therefore also be of use to such non-electrochemical scientists. I obtained most of the information included in this book from the publications of many scientists in this field. I would like to express my sincere thanks to all of them. I also would like to thank my coworkers for their cooperation, the editorial and production staff of Wiley-VCH for their help and support, and my wife for her assistance and patience.[ Last edited by 战国时代 on 2012-1-3 at 18:04 ] |
回复此楼» 本帖附件资源列表
-
欢迎监督和反馈：小木虫仅提供交流平台，不对该内容负责。
本内容由用户自主发布，如果其内容涉及到知识产权问题，其责任在于用户本人，如对版权有异议，请联系邮箱：xiaomuchong@tal.com - 附件 1 : electrochemistry in nonaqueous solutions.pdf
2012-01-03 18:04:07, 2.65 M
» 收录本帖的淘帖专辑推荐
 锂电资源共享 | ....锂电池┆_____ | 专业电子书 | 锂离子电池与科研 |
| 锂电技术共享 | 电化学基础-我的圣经 | 化学、化工与药学 | Lithium ions batteries |
| Nanobio | 电化学，腐蚀，阴极沉积，阳极氧化 | 粒子宇宙生命 | 专业书籍集锦 |
| 表征 软件应用 实用贴 | 学术期刊论文 | 电化学相关电子书收录 | 如是我闻 |
| 电化学 | 什么情况 | 材料学资料 |
» 猜你喜欢
深圳大学高等研究院赵伟课题组招收化学调剂生
已经有3人回复
-
青岛大学固态电池研究团队招收材料、化学、物理等方向博士研究生
已经有32人回复
-
物理化学论文润色/翻译怎么收费?
已经有131人回复
-
化学工程085602 305分求调剂
已经有17人回复
-
龋病与牙周病的表述
已经有1人回复
-
070300化学求调剂
已经有12人回复
-
武汉纺织大学全国重点实验室杨应奎教授团队拟招17-19位硕博生！
已经有0人回复
-
材料与化工专硕接受跨专业调剂（重庆市属高校）
已经有0人回复
-
武汉纺织大学全国重点实验室杨应奎教授团队拟招17-19位硕博生！
已经有0人回复
-
070300 化学学硕 初试357分 b区求调剂
已经有1人回复
-
上海工程技术大学生态与功能纺织品开发研究团队招收学硕专硕研究生
已经有0人回复
» 本主题相关价值贴推荐，对您同样有帮助:
- 可以用来做超级电容器的粘结剂的高分子材料有哪些指标要求？
已经有9人回复
- 锌粒在氯化铵溶液中如何转化为锌粉？
已经有3人回复
- 【资源】常用的电化学书籍归纳
已经有50人回复
38楼2012-01-04 17:03:51
简单回复
chgyhit2楼
2012-01-03 18:21
回复
五星好评 
fotc4楼
2012-01-03 19:36
回复
五星好评 顶一下，感谢分享！
2012-01-03 19:45
回复
五星好评 顶一下，感谢分享！
2012-01-03 20:04
回复
五星好评 顶一下，感谢分享！
xiandan7楼
2012-01-03 20:10
回复
五星好评 顶一下，感谢分享！
2012-01-03 20:16
回复
五星好评 顶一下，感谢分享！
zhhlei9楼
2012-01-03 20:16
回复
五星好评 顶一下，感谢分享！
tjk10楼
2012-01-03 20:18
回复
五星好评 顶一下，感谢分享！
xiejf11楼
2012-01-03 20:24
回复
五星好评 顶一下，感谢分享！
wuzhaoguo9012楼
2012-01-03 20:30
回复
五星好评 顶一下，感谢分享！
fjgxs13楼
2012-01-03 23:01
回复
五星好评 顶一下，感谢分享！
geoxung14楼
2012-01-04 00:12
回复
五星好评 顶一下，感谢分享！
