| 查看: 15795 | 回复: 271 | |||||||||||||||||||||
| 【奖励】 本帖被评价229次，作者战国时代增加金币 181 个 | |||||||||||||||||||||
| 本帖产生 1 个 ECEPI ，点击这里进行查看 | |||||||||||||||||||||
[资源]
【电化学基础书籍】electrochemistry in nonaqueous solutions
|
|||||||||||||||||||||
|
Kosuke Izutsu (writer) Electrochemistry inNonaqueous Solutions A majority of chemical reactions are carried out in solution. The use of a solvent as reaction medium makes it easy to control reaction conditions such as tempera- ture, pressure, pH, rate of mass transfer, and concentration of reactant. Water is the most popular solvent. However, by using appropriate non-aqueous solvents, substances that are insoluble in water can be dissolved, substances that are un- stable in water remain stable, and chemical reactions that are impossible in water become possible. The reaction environments are markedly wider in non-aqueous solvents than in water. The widespread use of non-aqueous solvents, especially dipolar aprotic solvents, began in the 1950s in various fields of pure and applied chemistry and has con- tributed greatly to later advances in chemical sciences and technologies. From the very beginning, electrochemistry in non-aqueous solutions has played an impor- tant role in exploring new chemical possibilities as well as in providing the meth- ods to evaluate static solvent effects on various chemical processes. Moreover, many new electrochemical technologies have been developed using non-aqueous solvents. Recently, electrochemistry in non-aqueous solutions has made enormous progress: the dynamic solvent effects on electrochemical processes have been greatly elucidated and solvent effects are now understood much better than be- fore. On the other hand, however, it is also true that some useful solvents have properties that are problematic to human health and the environment. Today, ef- forts are being made, under the framework of ‘green chemistry’, to find environ- mentally benign media for chemical processes, including harmless non-aqueous solvents, immobilized solvents, ionic liquids, supercritical fluids, aqueous sys- tems, and even solventless reaction systems. For electrochemical purposes, replac- ing hazardous solvents by harmless solvents, ionic liquids and supercritical fluids appears to be promising. This book was written to provide readers with some knowledge of electrochem- istry in non-aqueous solutions, from its fundamentals to the latest developments, including the current situation concerning hazardous solvents. The book is di- vided into two parts. Part I (Chapters 1 to 4) contains a discussion of solvent prop- erties and then deals with solvent effects on chemical processes such as ion solva- tion, ion complexation, electrolyte dissociation, acid-base reactions and redox reac- tions. Such solvent effects are of fundamental importance in understanding chem- istry in non-aqueous solutions; furthermore, their quantitative evaluations are of- ten carried out by means of electrochemical techniques. Part II (Chapters 5 to 12) mainly deals with the use of electrochemical techniques in non-aqueous solu- tions. In Chapter 5, the fundamentals of various electrochemical techniques are outlined in preparation for the following chapters. In Chapters 6 to 9, the applica- tions of potentiometry, conductimetry, polarography, voltammetry, and other new electrochemical techniques in non-aqueous solutions are discussed by focusing on the chemical information they provide. Chapters 10 and 11 examine methods of selecting and purifying the solvents and electrolytes of electrochemical impor- tance. Finally, in Chapter 12, some practical applications of non-aqueous solvents in modern electrochemical technologies are discussed. These include their use in batteries, capacitors and display devices, and such processes as electrolytic refin- ing, plating, synthesis and polymerization. The applicability of ionic liquids and supercritical fluids as environmentally benign media for electrochemical technol- ogy is also dealt with. Most chemists are familiar with chemistry in aqueous solutions. However, the common sense in aqueous solutions is not always valid in non-aqueous solutions. This is also true for electrochemical measurements. Thus, in this book, special emphasis is placed on showing which aspects of chemistry in non-aqueous solu- tions are different from chemistry in aqueous solutions. Emphasis is also placed on showing the differences between electrochemical measurements in non-aque- ous systems and those in aqueous systems. The importance of electrochemistry in non-aqueous solutions is now widely recognized by non-electrochemical scientists – for example, organic and inorganic chemists often use cyclic voltammetry in aprotic solvents in order to determine redox properties, electronic states, and reac- tivities of electroactive species, including unstable intermediates. This book will therefore also be of use to such non-electrochemical scientists. I obtained most of the information included in this book from the publications of many scientists in this field. I would like to express my sincere thanks to all of them. I also would like to thank my coworkers for their cooperation, the editorial and production staff of Wiley-VCH for their help and support, and my wife for her assistance and patience.[ Last edited by 战国时代 on 2012-1-3 at 18:04 ] |
回复此楼» 本帖附件资源列表
-
欢迎监督和反馈：小木虫仅提供交流平台，不对该内容负责。
本内容由用户自主发布，如果其内容涉及到知识产权问题，其责任在于用户本人，如对版权有异议，请联系邮箱：xiaomuchong@tal.com - 附件 1 : electrochemistry in nonaqueous solutions.pdf
2012-01-03 18:04:07, 2.65 M
» 收录本帖的淘帖专辑推荐
 锂电资源共享 | ....锂电池┆_____ | 专业电子书 | 锂离子电池与科研 |
| 锂电技术共享 | 电化学基础-我的圣经 | 化学、化工与药学 | Lithium ions batteries |
| Nanobio | 电化学，腐蚀，阴极沉积，阳极氧化 | 粒子宇宙生命 | 专业书籍集锦 |
| 表征 软件应用 实用贴 | 学术期刊论文 | 电化学相关电子书收录 | 如是我闻 |
| 电化学 | 什么情况 | 材料学资料 |
» 猜你喜欢
Renlab@monash全奖博士机会，最后三天！
已经有0人回复
-
今年面上没有消息，想来是没了，散个金攒攒人品，为明年祈福
已经有698人回复
-
物理化学论文润色/翻译怎么收费?
已经有80人回复
-
合肥工业大学854仪器技术综合专业课考研
已经有0人回复
-
27年电化学博士毕业，想找海外QS前50的高校读博后求推荐
已经有3人回复
-
27年电池/材料类博士申请
已经有2人回复
-
2027年博士申请或转博科研助理 求推荐
已经有1人回复
-
请问谁有2025最新影响因子Excel表？金币求助！
已经有53人回复
-
氯化钠与有机磺酸分离
已经有1人回复
-
瑞典-博后-固态电池-粘结剂-锂离子电池方向
已经有53人回复
» 本主题相关价值贴推荐，对您同样有帮助:
- 可以用来做超级电容器的粘结剂的高分子材料有哪些指标要求？
已经有9人回复
- 锌粒在氯化铵溶液中如何转化为锌粉？
已经有3人回复
- 【资源】常用的电化学书籍归纳
已经有50人回复
94楼2012-03-13 11:20:10
38楼2012-01-04 17:03:51
3楼2012-01-03 19:29:31
简单回复
chgyhit2楼
2012-01-03 18:21
回复
五星好评 
fotc4楼
2012-01-03 19:36
回复
五星好评 顶一下，感谢分享！
2012-01-03 19:45
回复
五星好评 顶一下，感谢分享！
2012-01-03 20:04
回复
五星好评 顶一下，感谢分享！
xiandan7楼
2012-01-03 20:10
回复
五星好评 顶一下，感谢分享！
2012-01-03 20:16
回复
五星好评 顶一下，感谢分享！
zhhlei9楼
2012-01-03 20:16
回复
五星好评 顶一下，感谢分享！
tjk10楼
2012-01-03 20:18
回复
五星好评 顶一下，感谢分享！
xiejf11楼
2012-01-03 20:24
回复
五星好评 顶一下，感谢分享！
wuzhaoguo9012楼
2012-01-03 20:30
回复
五星好评 顶一下，感谢分享！
fjgxs13楼
2012-01-03 23:01
回复
五星好评 顶一下，感谢分享！
geoxung14楼
2012-01-04 00:12
回复
五星好评 顶一下，感谢分享！
wenfucjb115楼
2012-01-04 08:10
回复
五星好评 顶一下，感谢分享！
wenfucjb116楼
2012-01-04 08:10
回复
tanyutou17楼
2012-01-04 08:11
回复
三星好评 顶一下，感谢分享！
whcj18楼
2012-01-04 08:12
回复
五星好评 顶一下，感谢分享！
dongstronger19楼
2012-01-04 08:14
回复
五星好评 顶一下，感谢分享！
蓝云幽梦20楼
2012-01-04 08:27
回复
五星好评 顶一下，感谢分享！
Dian253821楼
2012-01-04 08:31
回复
五星好评 顶一下，感谢分享！
phross22楼
2012-01-04 08:46
回复
三星好评 顶一下，感谢分享！
dgf200823楼
2012-01-04 08:49
回复
五星好评 顶一下，感谢分享！
xshbo24楼
2012-01-04 08:54
回复
一般 顶一下，感谢分享！
qybstone25楼
2012-01-04 09:08
回复
五星好评 顶一下，感谢分享！
fmbs11026楼
2012-01-04 09:09
回复
五星好评 顶一下，感谢分享！
xiaoshm27楼
2012-01-04 09:13
回复
五星好评 顶一下，感谢分享！
nanost28楼
2012-01-04 09:14
回复
五星好评 顶一下，感谢分享！
zhangxiufly29楼
2012-01-04 09:42
回复
五星好评 顶一下，感谢分享！
cuimeng37330楼
2012-01-04 09:44
回复
五星好评 顶一下，感谢分享！
小赤兔31楼
2012-01-04 10:22
回复
五星好评 顶一下，感谢分享！
hitdulei32楼
2012-01-04 13:27
回复
五星好评 顶一下，感谢分享！
zcx22333楼
2012-01-04 14:33
回复
五星好评 顶一下，感谢分享！
q55734楼
2012-01-04 15:07
回复
五星好评 顶一下，感谢分享！
peilsisi35楼
2012-01-04 15:46
回复
五星好评 顶一下，感谢分享！
2012-01-04 16:04
回复
五星好评 顶一下，感谢分享！
taosong2137楼
2012-01-04 16:43
回复
五星好评 顶一下，感谢分享！
lh61039楼
2012-01-04 17:25
回复
五星好评 顶一下，感谢分享！
zxh16840楼
2012-01-04 17:55
回复
三星好评 顶一下，感谢分享！
zg_503a41楼
2012-01-04 18:11
回复
五星好评 顶一下，感谢分享！
chemhehe42楼
2012-01-04 18:18
回复
五星好评 顶一下，感谢分享！
weizhang1243楼
2012-01-04 19:13
回复
五星好评 顶一下，感谢分享！
gczhong0844楼
2012-01-04 19:37
回复
五星好评 顶一下，感谢分享！
fulllove45楼
2012-01-04 19:46
回复
五星好评 顶一下，感谢分享！
suqdu0246楼
2012-01-04 21:53
回复
五星好评 顶一下，感谢分享！
杨sir47楼
2012-01-04 23:02
回复
五星好评 顶一下，感谢分享！
i16848楼
2012-01-04 23:13
回复
五星好评 顶一下，感谢分享！
yuzhbt49楼
2012-01-05 00:09
回复
五星好评 顶一下，感谢分享！
ans50楼
2012-01-05 00:39
回复
五星好评 顶一下，感谢分享！
20