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Õâ¸öÊÇÓйس¬·Ö×Ó»¯Ñ§ÎÄÏ׵ķÒëÍû´óÉñÖ¸µã A linear-hyperbranched supramolecular amphiphile and its self-assembly into vesicles with great ductility Wei Tao, Yong liu, Binbin Jiang, Songrui Yu, Wei Huang, Yongfeng Zhou* and Deyue Yan* School of Chemistry & Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, P. R. China KEYWORDS: Linear-hyperbranched; Host-guest; Supramolecular amphiphiles; Vesicles. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 Supporting Information Placeholder ABSTRACT: A linear-hyperbranched supramolecular amphiphile (LHSA) was synthesized through the noncovalent coupling of adamantane (AD)- functionalized long alky chain (AD-Cn, n=12, 18, 30) and hyperbranched polyglycerol grafted from ¦Â-cyclodextrin (CD-g-HPG) by the specific AD/CD host-guest interactions. The obtained supramolecular Cn-b-HPGs self-assembled into unilamellar vesicles with great ductility, which could be disassembled readily under a competitive host of ¦Â-CD. |
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