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J.B. Goodenough 2010Äê·¢±íµÄChallenges for rechargeable batteries
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ºÜºÃµÄÎÄÏ×¹ØÓÚ rechargeable batteries Strategies for Li-ion batteries that are based on lithium-insertion compounds as cathodes are limited by the capacities of the cathodematerials and by the safe charging rates for Li transport across a passivating SEI layer on a carbon-based anode.With these strategies, it is difficult tomeet the commercial constraints on Li-ion batteries for plug-in-hybrid and all-electric vehicles as well as those for stationary electrical energy storage (EES) in a grid. Existing alternative strategies include a gaseous O2 electrode in a Li/air battery and a solid sulfur (S8) cathode in a Li/S battery. We compare the projected energy densities and EES efficiencies of these cells with those of a third alternative, a Li/Fe(III)/Fe(II) cell containing a redox couple in an aqueous solution as the cathode. Preliminary measurements indicate proof of concept, but implementation of this strategy requires identification of a suitable Li +-ion electrolyte. »ØÌûÊÇÃÀµÂ ![]() http://good.gd/1847768.htm |
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