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terry_well

ÈÙÓþ°æÖ÷ (ÖªÃû×÷¼Ò)

Ц°¾½¬ºý¡ª¡ªÂúÄÔ½¬ºý

ÓÅÐã°æÖ÷ÓÅÐã°æÖ÷

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wg423(½ð±Ò+50, ·­ÒëEPI+1): ´ú·¢½ð±Ò 2011-12-15 19:02:38
Abstract: In the melting extrusion process of the waste tire rubber powder (GTR) and high density polyethylene (HDPE), a high speed and high shear stress-induced twin-screw extruder screw method was used to study the effect of twin-screw extruder screw speed and extrusion the reaction temperature on the physical properties of thermoplastic mterials. Besides, the effects of the desulfurization agent butanol, alkyl polysulfides (420 or 450) and n-butylamine desulfurization of tire rubber blends (DGTR/HDPE) of gel content, flow rate, sol-infrared absorption spectroscopy and desulfurization tire rubber blends (DGTR/HDPE) ethylene propylene diene monomer rubber (EPDM) dynamic cross-linking process on the mechanical properties of such materials. It was shown that high-speed twin-screw extruder with high shear could  induce the scission of cross-linked network chain and reconciliation crosslinking reaction for waste tire rubber blends, causing desulfurization blends gel content decreased and reducing the size of non-melting gel particles and increasing the flow rate of the melt. In fact, those four kinds of promoters played obvious role to promote the desulfurization reaction, in which 450 or n-butylamine could promote the desulfurization effect and decrease content of desulfurization products gel and increase the flow rate of the melting. In this way, the physical properties of dynamic cross-linked thermoplastic elastomer were significantly improved. When n-butylamine as desulfurization agents was promoted, the best desulfurization reaction conditions (240 ¡æ and 1000r/min) under, DGTR / HDPE / EPDM dynamically crosslinked thermoplastic elastomer tensile strength and elongation at break were obtained as 12.5MPa and 440.6%, respectively.
Keywords: desulfurization, EPDM, elastomer, tire, accelerator;
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2Â¥2011-12-15 17:54:02
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alvarohao

Ìú¸Ëľ³æ (ÖøÃûдÊÖ)

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wg423(½ð±Ò+50, ·­ÒëEPI+1): ´ú·¢½ð±Ò 2011-12-15 19:02:48
Abstract£ºThe high shear stress inducing method, which was used to increase the screw revolving speed of the twin-screw extruder during the melt extrusion process of the waste tire rubber powder (GTR) and HDPE, was applied to study the influences on the gel content, melt flow rate, sol gel infrared absorption spectrum of the tire rubber desulfuration blends(DGTR/HDPE) and the mechanical properties of the tire rubber desulfuration blends(DGTR/HDPE)/ EPDM dynamical cross linking thermal plastic elastic body, by the screw revolving speed of the twin-screw extruder, the extrusion reaction temperature and the desulfuration accelerating agent, including the sec-butyl alcohol, the alkylphenol polysulfide(420 or 450) and the n-butylamine. The results showed that: the high shearing action of the co-rotating twin-screw extruder with high revolving speed could induce the chain scission and disassemble the cross linking reaction of the waste tire rubber blends, leading to the decrease of the gel content of the desulfuration blends, the decrease of the unmelted gel grain size and the increase of the melt flow rate; The four kinds of accelerating agents had an apparent effect of improving the desulfuration reaction, among which the 450 or the n-butylamine had better effect, leading to the decrease of the gel content of the desulfuration products, the increase of the melt flow rate and the apparent improvement of the mechanical properties of the dynamic cross linking thermal plastic elastic body; With the n-butylamine being the accelerating agent, under the best desulfuration reaction conditions£¨240¡æ and 1000r/min£©, the tensile strength and the elongation at break of the DGTR/HDPE/EPDM dynamic cross linking thermal plastic elastic body were 12.5Mpa and 440.6%, respectively.
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3Â¥2011-12-15 17:55:51
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