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jjxiang

捐助贵宾 (著名写手)

[求助] 翻译一段英文文献·····

MAF synthesis is relatively insensitive to the reaction condi-
tions because most of the common species presented in the
solution, such as anions and solvent molecules, can hardly
compete with the targeted metal azolate bonds, which is parti-
cularly true for those composed of soft metal ions and diazolates.
Nevertheless, the coordination affinity varies among different
species, including different azolates. Therefore, additional species
presented in the solution can either be innocent or act as a coor-
dination additive/buffer, a template, a counterion, and even a
coligand. Taking these into consideration, the reaction outcomes
can be more predictable

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fuaixiang

金虫 (小有名气)

【答案】应助回帖


jjxiang(金币+10, 翻译EPI+1): 2011-11-15 08:38:46
爱与雨下(金币+1): 2011-11-15 08:39:27
MAF合成对反应条件相对不敏感,因为溶液中存在的阴离子和溶剂分子等常见的成分几乎不能与靶金属唑键竞争,由软金属离子和二唑组成的键尤其如此。然而,不同成分(包括不同唑类)之间的协调亲和力不同。因此,溶液中存在的其他成分可能不起作用,也可能作为协调添加剂/缓冲剂、模板、反离子、甚至共同配体。如果将这些考虑进去,反应结果可能更具有可预测性。(azolate的翻译不太确定)
2楼2011-11-14 22:03:22
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