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Çë²»ÒªÔÚÏß·Ò룬лл~ 1.Oxidative Stability Index The OSI of the vegetable oils, fish oil, oil blends, SLs with added tocopherols and their controls are given in Table 3. Coconut oil had the highest oxidative stability in comparison to the other oils. This is due to the high content of saturated fatty acids in coconut oil, leading to a high resistance to oxidation. On the other hand, fish oil had the lowest OSI value (0.2 h at 110 C), and therefore the lowest resistance to oxidative deterioration. The low OSI value of fish oil is attributed to its high-unsaturated fatty acids content, especially the LCPUFAs. Although safflower and soybean oils, which contain high amounts of monounsaturated fatty acids (MUFAs) had lower OSI values than coconut oil, they also had better oxidative stability than fish oil (Table 3). The enzymatic interesterification reaction appeared to increase the susceptibility of the SLs to oxidation, as the OSI values of S1 and SFO decreased significantly from that of B1 and BFO (Table 3). Factors such as loss of tocopherols and phospholipids during the short-path distillation process might be associated with the low stability of S1 and SFO samples. However, the addition of tocopherols as an antioxidant to the SLs positively affected their oxidative stability. The OSI values of SIV and SFOV were significantly higher than those of S1and SFO (Table 3). Although antioxidant addition increased the oxidative stability of the SLs (Table 3), the presence of LCPUFAs also had an impact on the OSI values of these SLs, irrespective of their tocopherol content. The results in Table 3 show that the OSI values of SIV and SFOV at 110 C are more comparable to those of B1 and BFO, unlike the values of S1 and SFO at the same OSI temperature. 2.P-Anisidine Value The p-anisidine assay is used to quantify the carbonyl compounds present in oils as a means to determine the past history of the oil . The vegetable oils had very low PAV(Fig. 2), unlike fish oil, which had an initial P-AV greater than 1.0/g, and about 95% increase in this index after 72 h oxidation at 60 C. The oil blends both showed a P-AV less than 0.2 after 72 h of oxidation (Fig. 2). The high P-AV of fish oils is attributed to a high rate of secondary oxidation products formation, unlike in the vegetable oils and oil blends. Tocopherol addition as an antioxidant had a positive effect on the P-AV of the SLs throughout the accelerated oxidation period. Comparison of S1V and SFOV to B1, BFO, S1, and SFO shows that the tocopherol-fortified oils had lower P-AV (Fig. 2). This is expected due to the low formation of hydroperoxides in these fortified SLs. Since the peroxides have to be present before subsequent breakdown to secondary oxidation products, it follows that low hydroperoxide formation increased the oxidative stability of these oils. The SLs with added tocopherols had P-AV that are comparable to their respective starting oil blends. S1 and SFO on the other hand, had P-AV at 24 h that are comparable to P-AV values of the oil blends at 72 h of accelerated oxidation (Fig. 2). Fish oil, S1 and SFO had higher P-AV than other samples, which suggests low oxidative stability of these oils with respect to the other oils. |
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momo198548(½ð±Ò+80, ·ÒëEPI+1): ·Ç³£¸Ðл£¬ºÜºÃºÜÇ¿´ó£¡ 2011-11-04 15:18:52
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momo198548(½ð±Ò+80, ·ÒëEPI+1): ·Ç³£¸Ðл£¬ºÜºÃºÜÇ¿´ó£¡ 2011-11-04 15:18:52
°®ÓëÓêÏÂ(½ð±Ò+5): 2011-11-05 07:54:05
sltmac(½ð±Ò+10): 2011-11-09 10:14:53
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sltmac: »¶Ó³£À´ 2011-11-09 10:15:01
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