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[资源] Pd催化的C-C耦合反应－ Chemical Review

Contents
1. Introduction 1
1.1. Catalysts 3
1.2. Mechanistic Aspects 4
2. Suzuki Reactions 5
2.1. Pd on Carbon (Pd/C) 5
2.1.1. In the Presence of Phosphine Ligands 5
2.1.2. In the Absence of Phosphine Ligands 6
2.1.3. Ligand-Free Suzuki Coupling in Aqueous
Surfactants
8
2.1.4. Ligand-Free Suzuki Coupling under
Microwave or Ultrasound Conditions
8
2.2. Palladium on Metal Oxides 9
2.2.1. Palladium-Doped KF/Al2O3 9
2.2.2. Iron Oxide Nanoparticle-Supported
Pd-N-Heterocyclic Carbene Complexes
10
2.2.3. Palladium-Containing Perovskites 11
2.2.4. Miscellaneous Metal Oxides 11
2.3. Pd on Porous Aluminosilicates 11
2.4. Pd on Modified Silica 12
2.5. Pd on Clays and Other Inorganic Materials 13
3. Heck Reactions 14
3.1. Pd on Carbon (Pd/C) 14
3.2. Pd on Metal Oxides 17
3.3. Pd on Microporous and Mesoporous
Supports
18
3.4. Pd on Modified Silica (Organic-Inorganic
Hybrid Support)
19
3.5. Pd on Clay and Other Inorganic Materials 21
4. Sonogashira Reactions 22
4.1. Pd on Carbon (Pd/C) 22
4.1.1. In Anhydrous Media 22
4.1.2. In Organic Solvent/Water Mixtures 23
4.1.3. Copper-Free and Ligand-Free
Sonogashira Coupling
25
4.2. Pd on Metal Oxides 26
4.3. Pd on Microporous and Mesoporous
Supports
26
4.4. Pd on Modified Silica 27
4.5. Pd on Clay and Other Inorganic Materials 27
5. Stille, Fukuyama, and Negishi Reactions 27
5.1. Stille Reactions 27
5.1.1. Pd on Carbon (Pd/C) 27
5.1.2. Palladium on KF/Al2O3 27
5.1.3. Pd on Modified Silica (SiO2/TEG/Pd) 27
5.2. Fukuyama Reactions 27
5.2.1. Pd on Carbon (Pd/C) 27
5.2.2. Pd(OH)2 on Carbon (Perlman’s Catalyst) 28
5.3. Pd/C-Catalyzed Negishi Reactions 28
6. Ullmann-Type Coupling Reactions 29
6.1. Pd/C-Catalyzed Aryl-Aryl Coupling 29
6.2. Pd/C-Catalyzed Homocoupling of Vinyl
Halides
30
6.3. Pd/C-Catalyzed Intramolecular Coupling of
Aryl and Vinyl Halides
30
7. Homocoupling of Arylboronic Acids, Pyridines,
and Alkynes
30
7.1. Pd/C-Catalyzed Homocoupling of Arylboronic
Acids (Suzuki-Type Homocoupling)
30
7.2. Pd/C-Catalyzed Homocoupling of Pyridines 30
7.3. Pd/C-Catalyzed Homocoupling of Alkynes
(Glaser-Type Coupling)
32
8. Other Coupling Reactions 32
8.1. Cyanation of Aryl Bromides 32
8.2. Carbonylations 32
8.3. R-Arylations of Diethyl Malonate 33
8.4. Arylations of Aromatic Compounds 33
8.5. Allylations 34
8.6. Intermolecular Heck-Type Coupling 34
9. Pd on Solid Support in Tandem Reactions 35
9.1. Sonogashira Coupling in Tandem Reactions 35
9.2. Heck Coupling in Tandem Reactions 36
10. Conclusions and Perspectives 37
11. Abbreviations 38
12. Acknowledgments 38
13. References
不知道怎么把PDF文件分成两个文件传递哦，单个太大了

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1楼 2006-12-21 22:04:35

已阅回复此楼关注TA 给TA发消息送TA红花 TA的回帖

rabbit7708

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可以用WinRAR的，压缩时里面有选项（可以在文件上点右键，添加到压缩文件，在这个窗口的左下角有这个选项），可以分卷压缩的，然后就可以按需要压成多个文件了，解压时点第一个就又合并解压为一个PDF文件了！
或者可以传到56信箱里，共享一下！
您可以看看小木虫内的56邮箱使用教程：
http://muchong.com/bbs/viewthread.php?tid=172014&fpage=1