| 查看: 858 | 回复: 4 | ||
| 当前主题已经存档。 | ||
[资源]
Pd催化的C-C耦合反应－ Chemical Review
|
||
|
Contents 1. Introduction 1 1.1. Catalysts 3 1.2. Mechanistic Aspects 4 2. Suzuki Reactions 5 2.1. Pd on Carbon (Pd/C) 5 2.1.1. In the Presence of Phosphine Ligands 5 2.1.2. In the Absence of Phosphine Ligands 6 2.1.3. Ligand-Free Suzuki Coupling in Aqueous Surfactants 8 2.1.4. Ligand-Free Suzuki Coupling under Microwave or Ultrasound Conditions 8 2.2. Palladium on Metal Oxides 9 2.2.1. Palladium-Doped KF/Al2O3 9 2.2.2. Iron Oxide Nanoparticle-Supported Pd-N-Heterocyclic Carbene Complexes 10 2.2.3. Palladium-Containing Perovskites 11 2.2.4. Miscellaneous Metal Oxides 11 2.3. Pd on Porous Aluminosilicates 11 2.4. Pd on Modified Silica 12 2.5. Pd on Clays and Other Inorganic Materials 13 3. Heck Reactions 14 3.1. Pd on Carbon (Pd/C) 14 3.2. Pd on Metal Oxides 17 3.3. Pd on Microporous and Mesoporous Supports 18 3.4. Pd on Modified Silica (Organic-Inorganic Hybrid Support) 19 3.5. Pd on Clay and Other Inorganic Materials 21 4. Sonogashira Reactions 22 4.1. Pd on Carbon (Pd/C) 22 4.1.1. In Anhydrous Media 22 4.1.2. In Organic Solvent/Water Mixtures 23 4.1.3. Copper-Free and Ligand-Free Sonogashira Coupling 25 4.2. Pd on Metal Oxides 26 4.3. Pd on Microporous and Mesoporous Supports 26 4.4. Pd on Modified Silica 27 4.5. Pd on Clay and Other Inorganic Materials 27 5. Stille, Fukuyama, and Negishi Reactions 27 5.1. Stille Reactions 27 5.1.1. Pd on Carbon (Pd/C) 27 5.1.2. Palladium on KF/Al2O3 27 5.1.3. Pd on Modified Silica (SiO2/TEG/Pd) 27 5.2. Fukuyama Reactions 27 5.2.1. Pd on Carbon (Pd/C) 27 5.2.2. Pd(OH)2 on Carbon (Perlman’s Catalyst) 28 5.3. Pd/C-Catalyzed Negishi Reactions 28 6. Ullmann-Type Coupling Reactions 29 6.1. Pd/C-Catalyzed Aryl-Aryl Coupling 29 6.2. Pd/C-Catalyzed Homocoupling of Vinyl Halides 30 6.3. Pd/C-Catalyzed Intramolecular Coupling of Aryl and Vinyl Halides 30 7. Homocoupling of Arylboronic Acids, Pyridines, and Alkynes 30 7.1. Pd/C-Catalyzed Homocoupling of Arylboronic Acids (Suzuki-Type Homocoupling) 30 7.2. Pd/C-Catalyzed Homocoupling of Pyridines 30 7.3. Pd/C-Catalyzed Homocoupling of Alkynes (Glaser-Type Coupling) 32 8. Other Coupling Reactions 32 8.1. Cyanation of Aryl Bromides 32 8.2. Carbonylations 32 8.3. R-Arylations of Diethyl Malonate 33 8.4. Arylations of Aromatic Compounds 33 8.5. Allylations 34 8.6. Intermolecular Heck-Type Coupling 34 9. Pd on Solid Support in Tandem Reactions 35 9.1. Sonogashira Coupling in Tandem Reactions 35 9.2. Heck Coupling in Tandem Reactions 36 10. Conclusions and Perspectives 37 11. Abbreviations 38 12. Acknowledgments 38 13. References 不知道怎么把PDF文件分成两个文件传递哦，单个太大了 |
回复此楼» 猜你喜欢
华侨大学（厦门）——急招化工/材料/化学/能动——26年9月份博士
已经有18人回复
-
海南大学光电功能分子基材料课题组招收2026年攻读学位博士生
已经有10人回复
-
专业论文润色/翻译怎么收费?
已经有130人回复
-
瑞典林雪平大学范立洲课题组现招聘博士后、岗位制博士生
已经有1人回复
-
求有机合成大神指点三硫酸乙烯酯（CAS：2793408-99-6）的合成路线
已经有10人回复
-
钯炭、铂炭、钌炭等加氢催化剂
已经有21人回复
-
AgI的FT-IR谱图
已经有1人回复
-
添加了水性硬脂酸钙乳液后泡沫多
已经有1人回复
 可以用WinRAR的，压缩时里面有选项（可以在文件上点右键，添加到压缩文件，在这个窗口的左下角有这个选项），可以分卷压缩的，然后就可以按需要压成多个文件了，解压时点第一个就又合并解压为一个PDF文件了！ 或者可以传到56信箱里，共享一下！ 您可以看看小木虫内的56邮箱使用教程： http://muchong.com/bbs/viewthread.php?tid=172014&fpage=1 |
2楼2006-12-22 08:47:34
3楼2006-12-22 15:14:48
5楼2006-12-22 17:46:29
简单回复
didiguo4楼
2006-12-22 16:57
回复
5