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标题：Oxygen reduction mechanism on corroded zinc
摘要：The mechanism of oxygen reduction on the as-polished and corroded zinc specimens has been studied using a rotating ring disc
electrode (RRDE) system. On the as-polished surface, oxygen was reduced into two distinct steps. In the first step, about 44% of O2
was reduced to H2O2 in a 2-electron reaction with the rest being reduced to OH in a 4-electron reaction. On the other hand, in the
second step, with the increase of overpotential O2 was almost exclusively reduced to OH in a 4-electron reaction. The first step
reduction occurred on an air-formed oxide-covered surface at more positive potential than 1.2 V vs. Ag/AgCl and the second step
reduction (E < 1.2 V) took place on a semi-uniformly active surface. On the corroded surface, the second step was not distinctly
observed on the polarization curve, because reduction of the zinc corrosion products simultaneously took place around 1.2 V. The
O2 reduction in the first step was inhibited by deposition of the corrosion products, though the ratio of amount of O2 reduced to
OH in a 4-electron reaction was larger than that on the as-polished surface. The mechanism of oxygen reduction is discussed on the
basis of results obtained from the RRDE experiment.

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