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taozhikai

金虫 (著名写手)


[资源] nature chemistry最新:FeOx负载Pt催化CO氧化

Platinum-based heterogeneous catalysts are critical to many important commercial chemical processes, but their efficiency is extremely low on a per metal atom basis, because only the surface active-site atoms are used. Catalysts with singleatomdispersions are thus highly desirable to maximize atom efficiency, but making them is challenging. Here we report the synthesis of a single-atom catalyst that consists of only isolated single Pt atoms anchored to the surfaces of iron oxidenanocrystallites. This single-atom catalyst has extremely high atom efficiency and shows excellent stability and highactivity for both CO oxidation and preferential oxidation of CO in H2. Density functional theory calculations show that thehigh catalytic activity correlates with the partially vacant 5d orbitals of the positively charged, high-valent Pt atoms, whichhelp to reduce both the COadsorption energy and the activation barriers for CO oxidation.
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量子幽灵

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我对这个方向很感兴趣,顶一下
17楼2011-08-05 21:40:25
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zlin2楼
2011-07-22 15:15   回复  
五星好评  顶一下,感谢分享!
kinmer3楼
2011-07-22 15:27   回复  
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风枫4楼
2011-07-22 15:51   回复  
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aishan5楼
2011-07-22 18:39   回复  
五星好评  感谢分享!
songqixia6楼
2011-07-23 08:27   回复  
五星好评  顶一下,感谢分享!
李飞明7楼
2011-07-23 10:37   回复  
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2011-07-23 11:20   回复  
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2008guoym9楼
2011-07-23 18:30   回复  
三星好评  顶一下,感谢分享!
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2011-07-23 19:15   回复  
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2011-07-23 20:36   回复  
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杨子煜12楼
2011-07-24 10:09   回复  
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2011-07-24 12:36   回复  
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