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The key advantage of using vertically aligned one-dimensional (1-D) metal oxide nanostructures as A component for  the hybrid devices is the capability to provide direct and stable   pathways for the transport of photogenerated electrons toward
the collection electrode. The bulk heterojunction with vertically  aligned 1-D nanochannels for electron transportation has been  regarded as an ideal structure for polymer-based solar cells. ZnO has recently been of great interest in the preparation of  such aligned 1-D structures for this purpose, due to its high
electron mobility and easy availability at low temperature by  controllable synthesis. The aligned ZnO nanorod arrays prepared  by hydrothermal reaction  have normally been used for hybrid  polymer/ZnO solar cells, but the power conversion efficiency  (¦Ç)of0.2 0.5% is not high yet. The hydrothermal method  generally produces ZnO nanostructures containing many deep  level defects,  which will significantly influence the transport  of photogenerated charges toward the collection electrode by  trapping/detrapping electrons.  In contrast, the ZnO nanostructures synthesized by electrodeposition contain much less defects, offering a low-temperature technique for the low-cost  growth of high quality ZnO crystals. Very recently, Atienzar  and co-workers  showed the first application of the electrodeposited ZnO nanorod arrays for hybrid polymer/ZnO solar cell  devices with an efficiency of ¦Ç 0.025% under AM 1.5  illumination. Even though dramatic improvements have been  achieved on the device construction and processing of the   photoactive layer of polymer/ZnO nanorod array devices,
the relationship between the intrinsic property of ZnO nanorods  and the device performance, which is crucially important for  improving cell performance, still remains unclear.
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yanjiao12(½ð±Ò+30, ·­ÒëEPI+1): Ì«ºÃÁË£¬Ð»Ð» 2011-07-12 15:39:24
yanjiao12(½ð±Ò+30): 2011-07-12 19:50:40
The key advantage of using vertically aligned one-dimensional (1-D) metal oxide nanostructures as A component for  the hybrid devices is the capability to provide direct and stable   pathways for the transport of photogenerated electrons toward the collection electrode.
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The bulk heterojunction with vertically  aligned 1-D nanochannels for electron transportation has been  regarded as an ideal structure for polymer-based solar cells. ZnO has recently been of great interest in the preparation of  such aligned 1-D structures for this purpose, due to its high electron mobility and easy availability at low temperature by  controllable synthesis.
ÓÃÀ´ÊäË͵ç×ÓµÄÓÉ´¹Ö±Õë״һάÄÉÃ׹ܵÀ¹¹³ÉµÄÌåÒìÖʽá²ÄÁϱ»ÈÏΪÊÇÖÆ±¸¾ÛºÏÎï»ùÌ«ÑôÄÜµç³ØµÄÀíÏë²ÄÁÏ¡£ÎªÁË´ïµ½´ËÄ¿µÄ£¬ÓÃZnOÀ´ÖƱ¸ÕâÖÖÕë״һά½á¹¹²ÄÁϽüÀ´ÒýÆðÁËÈËÃǹ㷺µÄÐËȤ£¬ÕâÊÇÓÉÓÚZnOµÄ¸ßµç×ÓÇ¨ÒÆÂÊÒÔ¼°ÆäÔÚµÍÎÂϵĿɿغϳɡ£
The aligned ZnO nanorod arrays prepared  by hydrothermal reaction  have normally been used for hybrid  polymer/ZnO solar cells, but the power conversion efficiency  (¦Ç)of0.2 0.5% is not high yet.
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The hydrothermal method  generally produces ZnO nanostructures containing many deep  level defects,  which will significantly influence the transport  of photogenerated charges toward the collection electrode by  trapping/detrapping electrons.
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In contrast, the ZnO nanostructures synthesized by electrodeposition contain much less defects, offering a low-temperature technique for the low-cost  growth of high quality ZnO crystals.
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Very recently, Atienzar  and co-workers  showed the first application of the electrodeposited ZnO nanorod arrays for hybrid polymer/ZnO solar cell  devices with an efficiency of ¦Ç 0.025% under AM 1.5  illumination.
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Even though dramatic improvements have been  achieved on the device construction and processing of the   photoactive layer of polymer/ZnO nanorod array devices,the relationship between the intrinsic property of ZnO nanorods  and the device performance, which is crucially important for  improving cell performance, still remains unclear.
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