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lq2009-2012

木虫 (正式写手)

[求助] 水与配合物

游离水或者配位水对配合物性质方面比如磁性,荧光等有影响吗,最好提供相关文献
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xingyu6203

金虫 (著名写手)


drg1984(金币+1): 感谢应助! 2011-07-11 12:58:25
水及氢键对荧光,磁性等的影响: (1) Encapsulation of discrete (H2O)12 clusters in a 3D three-fold interpenetrating metal–organic framework host with (3,4)-connected topology. Dalton Trans., 2010, 39, 6187–6189
(2)An Unusual Three-Dimensional Water Cluster in Metal-Organic Frameworks Based on ZnX2 (X = ClO4,BF4) and an Azo-Functional Ligand. Cryst. Growth Des. 2010, 10, 2054-2056.
(3) An unprecedented nanoporous and fluorescent supramolecular
framework with an SrAl2 topology controllably synthesized from a
flexible ditopic acid. Chem. Commun., 2007, 4416–4418
(4) Crystal-to-Crystal Transformation from a Chain Compound to a Layered
Coordination Polymer. Chem. Asian J. 2011. doi.org/10.1002/asia.201100222
幸福就是每天吃饱了撑着睡觉
3楼2011-07-10 22:58:46
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knight1014

至尊木虫 (著名写手)

【答案】应助回帖


lq2009-2012(金币+15): 谢谢了! 2011-07-10 22:56:06
drg1984(金币+1): 感谢应助! 2011-07-11 08:58:07
孔道中含有水对配合物荧光产生了影响两篇:(a) Jun-Ling Song, Chong Lei, and Jiang-Gao Mao,Syntheses, Crystal Structures, and Luminescent Properties of Novel Layered Lanthanide Sulfonate?Phosphonates, Inorg. Chem. 2004, 43, 5630-5634. (b) Xiao-Qiang Yao, Ming-Dao Zhang, Jin-Song Hu, Yi-Zhi Li, Zi-Jian Guo, He-Gen Zheng, Two Porous Zinc Coordination Polymers with (10,3) Topological Feature Based On a N-centered Tripodal Ligand and The Conversion of (10,3)-d Subnet to (10,3)-a Subnet. Cryst. Growth Des. 2011, 11(7), 3039–3044.
2楼2011-07-10 20:14:40
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