| 查看: 582 | 回复: 1 | ||
| 本帖产生 1 个 翻译EPI ，点击这里进行查看 | ||
wo357026239铜虫 (正式写手)
|
[求助]
摘要翻译（中译英）
|
|
| 本文以芘为前体，合成了五个芘的衍生物，包括两个含溴化合物（1-溴芘和1,3,6,8-四溴芘）、1-芘硼酸、1,3,6,8-四（三甲基硅乙炔）芘和一个加氢化合物（1,2,3,6,7,8-六氢芘）。各种衍生物合成方案如下：（1）以溴作为溴化剂对芘进行溴化反应，控制溴化剂的用量，使发生单溴化反应得到1-溴芘；（2）同样以溴作为溴化剂对芘进行四溴化反应，使溴化剂的用量稍高于理论用量，反应完成后得到1,3,6,8-四溴芘；（3）1-溴芘与正丁基锂和硼酸三甲酯在低温下反应合成1-芘硼酸；（4）1,3,6,8-四溴芘与三甲基硅乙炔等在二异丙胺和四氢呋喃混合溶剂中反应生成1,3,6,8-四（三甲基硅乙炔）芘；（5）以钠和异戊醇反应提供氢源，使芘发生加氢反应得到1,2,3,6,7,8-六氢芘。对部分反应进行了反应条件的优化，对五个芘衍生物全部进行了红外光谱光谱分析。 |
回复此楼» 猜你喜欢
投稿返修后收到这样的回复，还有希望吗
已经有7人回复
-
压汞仪和BET测气凝胶孔隙率
已经有4人回复
-
博士申请都是内定的吗？
已经有14人回复
-
博士申请
已经有3人回复
-
谈谈两天一夜的“延安行”
已经有13人回复
-
氨基封端PDMS和HDI反应快速固化
已经有11人回复
-
之前让一硕士生水了7个发明专利，现在这7个获批发明专利的维护费可从哪儿支出哈？
已经有11人回复
-
论文投稿求助
已经有4人回复
-
Applied Surface Science 这个期刊。有哪位虫友投过的能把word模板发给我参考一下嘛
已经有3人回复
-
投稿精细化工
已经有6人回复
zuodg
铁杆木虫 (正式写手)
有为青年
- 翻译EPI: 180
- 应助: 5 (幼儿园)
- 贵宾: 0.015
- 金币: 6765.2
- 散金: 48
- 红花: 18
- 帖子: 500
- 在线: 285.5小时
- 虫号: 1055187
- 注册: 2010-07-10
- 性别: GG
- 专业: 外国语言
【答案】应助回帖
wo357026239(金币+20, 翻译EPI+1): 2011-06-10 21:07:41
|
Five pyrene derivatives, including two bromine-containing compounds (1 - bromo pyrene and 1, 3, 6, 8- tetrabromo pyrene), 1 - pyrene acid, 1,3,6,8 - Tetra (trimethylsilyl acetylene) pyrene and one hydrogenated compound (1, 2, 3, 6, 7, 8 - hexahydro pyrene) were synthesized with pyrene as precursor. Synthesis methods of the above derivatives were listed as below. 1) 1 - bromo pyrene was obtained through single bromination of pyrene with limited bromine; 2) 1, 3, 6, 8- tetrabromo pyrene were obtained through tetra-bromination of pyrene with bromine of slightly higher than the theoretical amount of usage; 3) 1 - pyrene acid was obtained through reaction of 1 - bromo pyrene with N-BuLi and trimethyl borate at low temperature; 4) 1,3,6,8 - Tetra (trimethylsilyl acetylene) pyrene was obtained through reaction of 1, 3, 6, 8- tetrabromo pyrene with trimethylsilyl acetylene in the mix solvents of diisopropylamine and THF; 5) 1, 2, 3, 6, 7, 8 - hexahydro pyrene was obtained through hydrogenation of pyrene with hydrogen, which was supplied through reaction of sodium with isoamyl alcohol. Some of reactions were optimized and total five pyrene derivatives were analyzed with IR. |
2楼2011-06-10 20:06:46