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(Chem.Rev2004)Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis
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Chem.Rev 2004 Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis 同时祝大家节日快乐！ [ Last edited by rabbit7708 on 2007-3-27 at 20:50 ] |
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berlin
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原贴见 http://muchong.com/bbs/viewthread.php?tid=221159 Itaru Nakamura and Yoshinori Yamamoto* Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan Received August 12, 2003 Contents 1. Introduction 2127 2. Intramolecular Reaction of 1,ö-Dienes and Enynes: Ring-Closing Metathesis (RCM) 2129 2.1. Ring-Closing Metathesis for Total Synthesis 2130 2.2. Tandem Olefin Metathesis 2130 2.3. Catalytic Enantioselective Olefin Metathesis 2139 2.4. Enyne Metathesis 2140 3. Intramolecular Reaction of 1,6-Dienes, -Enynes, and -Diynes: Cycloisomerization, Tandem Addition-Cyclization, and Cycloaddition 2140 3.1. Cycloisomerization 2141 3.2. Tandem Addition-Cyclization 2141 3.3. Cycloaddition 2143 3.3.1. [2 + 2 + 1]-Cycloaddition (Pauson-Khand Reaction) 2143 3.3.2. [2 + 2 + 2]-Cycloaddition 2145 3.3.3. [3 + 2]-Cycloaddition 2146 3.3.4. [4 + 2]-Cycloaddition 2146 3.3.5. [4 + 2 + 2]-, [5 + 2]-, and [6 + 2]-Cycloaddition 2147 4. Intramolecular Reaction of Alkenes, Allenes, and Alkynes Bearing N-H, O-H, CdO, and CdN Groups: Heterocyclization 2148 4.1. Alkenes 2149 4.2. Allenes 2151 4.3. Methylenecyclopropanes 2154 4.4. Alkynes 2154 4.4.1. Intramolecular Reaction of Alkynes with N-H and O-H Functional Groups 2154 4.4.2. Intramolecular Reaction of Alkynes with CdO and CdN Functional Groups 2158 5. Intra- and Intermolecular Cycloaddition of Carbon-Carbon and Carbon-Heteroatom Unsaturated Compounds: Hetero-Cycloaddition 2163 5.1. Hetero-[2 + 2]-Cycloaddition 2163 5.2. Hetero-[2 + 2 + 1]-Cycloaddition 2164 5.3. Hetero-[2 + 2 + 2]-Cycloaddition 2165 5.4. Hetero-[3 + 2]-Cycloaddition 2166 5.5. Hetero-[4 + 2]-Cycloaddition 2167 5.6. Hetero-[5 + 2]-Cycloaddition 2169 5.7. Carbonylation 2170 6. Intramolecular Reaction of Aryl and Vinyl Halides: Heck-, Suzuki-, and Stille-Type Reactions 2173 6.1. Carbon-Carbon Bond Formation 2173 6.2. Carbon-Heteroatom Bond Formation 2177 6.2.1. Intramolecular Coupling Reaction with a Heteroatom 2177 6.2.2. Amino-Heck Reaction 2178 6.2.3. Insertion of C-C Unsaturated Bondss Coupling with Heteroatoms 2179 6.2.4. Sonogashira Coupling of Terminal Alkynes Followed by Cyclization 2179 7. Intramolecular Reaction of Allyl Halides: Tsuji-Trost-Type Reaction 2180 7.1. Carbon-Carbon Bond Formation 2180 7.2. Carbon-Heteroatom Bond Formation 2180 7.2.1. Stereo- and Enantioselective Allylation 2180 7.2.2. Intra- and Intermolecular Alkoxyallylation Reactions of Allyl Carbonates 2181 7.2.3. Intra- and Intermolecular Reactions of Alkenyl Epoxides, Aziridines, and Thiiranes 2182 7.2.4. Amphiphilic Allylation via Bis-ð-allylpalladium, and the Reaction through ð-Allylpalladium Azide 2183 7.2.5. Intra- and Intermolecular Reaction of Propargyl Esters 2185 8. Intra- and Intermolecular Reaction of Diazo Compounds and Iminoiodinanes 2186 8.1. Carbon-Carbon Bond Formation 2187 8.1.1. Intramolecular Reaction of Diazo Compounds with a C-H Bond 2187 8.1.2. Intramolecular Reaction of Diazo Compounds with C-C Unsaturated Compounds 2187 8.2. Carbon-Heteroatom Bond Formation 2188 8.2.1. Intramolecular Reaction of Diazo Compounds with a N-H or O-H Bond 2188 8.2.2. Intramolecular Reaction of Diazo Compounds with Tertiary Amines, Ethers, and Thioethers 2189 8.2.3. Intra- and Intermolecular Reaction of Diazo Compounds with a CdO or CdN Bond 2189 8.2.4. Intra- and Intermolecular Reaction of Iminoiodinanes 2190 9. Conclusion 2190 10. References 2191 [ Last edited by berlin on 2006-10-3 at 20:40 ] |
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