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vutzisen

铁杆木虫 (著名写手)

master of organic chemistry

[交流] (Chem.Rev2004)Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis

Chem.Rev 2004
Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis

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[ Last edited by rabbit7708 on 2007-3-27 at 20:50 ]
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vutzisen

铁杆木虫 (著名写手)

master of organic chemistry

(Chem.Rev2004)Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis

Chem.Rev2004
Transition-Metal-Catalyzed Reactions in Heterocyclic Synthesis

[ Last edited by rabbit7708 on 2007-3-27 at 20:51 ]
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2楼2006-10-03 19:42:06
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berlin

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原贴见
http://muchong.com/bbs/viewthread.php?tid=221159

Itaru Nakamura and Yoshinori Yamamoto*
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
Received August 12, 2003
Contents
1. Introduction 2127
2. Intramolecular Reaction of 1,ö-Dienes and
Enynes: Ring-Closing Metathesis (RCM)
2129
2.1. Ring-Closing Metathesis for Total Synthesis 2130
2.2. Tandem Olefin Metathesis 2130
2.3. Catalytic Enantioselective Olefin Metathesis 2139
2.4. Enyne Metathesis 2140
3. Intramolecular Reaction of 1,6-Dienes, -Enynes,
and -Diynes: Cycloisomerization, Tandem
Addition-Cyclization, and Cycloaddition
2140
3.1. Cycloisomerization 2141
3.2. Tandem Addition-Cyclization 2141
3.3. Cycloaddition 2143
3.3.1. [2 + 2 + 1]-Cycloaddition (Pauson-Khand
Reaction)
2143
3.3.2. [2 + 2 + 2]-Cycloaddition 2145
3.3.3. [3 + 2]-Cycloaddition 2146
3.3.4. [4 + 2]-Cycloaddition 2146
3.3.5. [4 + 2 + 2]-, [5 + 2]-, and
[6 + 2]-Cycloaddition
2147
4. Intramolecular Reaction of Alkenes, Allenes, and
Alkynes Bearing N-H, O-H, CdO, and CdN
Groups: Heterocyclization
2148
4.1. Alkenes 2149
4.2. Allenes 2151
4.3. Methylenecyclopropanes 2154
4.4. Alkynes 2154
4.4.1. Intramolecular Reaction of Alkynes with
N-H and O-H Functional Groups
2154
4.4.2. Intramolecular Reaction of Alkynes with
CdO and CdN Functional Groups
2158
5. Intra- and Intermolecular Cycloaddition of
Carbon-Carbon and Carbon-Heteroatom
Unsaturated Compounds: Hetero-Cycloaddition
2163
5.1. Hetero-[2 + 2]-Cycloaddition 2163
5.2. Hetero-[2 + 2 + 1]-Cycloaddition 2164
5.3. Hetero-[2 + 2 + 2]-Cycloaddition 2165
5.4. Hetero-[3 + 2]-Cycloaddition 2166
5.5. Hetero-[4 + 2]-Cycloaddition 2167
5.6. Hetero-[5 + 2]-Cycloaddition 2169
5.7. Carbonylation 2170
6. Intramolecular Reaction of Aryl and Vinyl
Halides: Heck-, Suzuki-, and Stille-Type
Reactions
2173
6.1. Carbon-Carbon Bond Formation 2173
6.2. Carbon-Heteroatom Bond Formation 2177
6.2.1. Intramolecular Coupling Reaction with a
Heteroatom
2177
6.2.2. Amino-Heck Reaction 2178
6.2.3. Insertion of C-C Unsaturated Bondss
Coupling with Heteroatoms
2179
6.2.4. Sonogashira Coupling of Terminal
Alkynes Followed by Cyclization
2179
7. Intramolecular Reaction of Allyl Halides:
Tsuji-Trost-Type Reaction
2180
7.1. Carbon-Carbon Bond Formation 2180
7.2. Carbon-Heteroatom Bond Formation 2180
7.2.1. Stereo- and Enantioselective Allylation 2180
7.2.2. Intra- and Intermolecular Alkoxyallylation
Reactions of Allyl Carbonates
2181
7.2.3. Intra- and Intermolecular Reactions of
Alkenyl Epoxides, Aziridines, and
Thiiranes
2182
7.2.4. Amphiphilic Allylation via
Bis-ð-allylpalladium, and the Reaction
through ð-Allylpalladium Azide
2183
7.2.5. Intra- and Intermolecular Reaction of
Propargyl Esters
2185
8. Intra- and Intermolecular Reaction of Diazo
Compounds and Iminoiodinanes
2186
8.1. Carbon-Carbon Bond Formation 2187
8.1.1. Intramolecular Reaction of Diazo
Compounds with a C-H Bond
2187
8.1.2. Intramolecular Reaction of Diazo
Compounds with C-C Unsaturated
Compounds
2187
8.2. Carbon-Heteroatom Bond Formation 2188
8.2.1. Intramolecular Reaction of Diazo
Compounds with a N-H or O-H Bond
2188
8.2.2. Intramolecular Reaction of Diazo
Compounds with Tertiary Amines, Ethers,
and Thioethers
2189
8.2.3. Intra- and Intermolecular Reaction of
Diazo Compounds with a CdO or CdN
Bond
2189
8.2.4. Intra- and Intermolecular Reaction of
Iminoiodinanes
2190
9. Conclusion 2190
10. References 2191

[ Last edited by berlin on 2006-10-3 at 20:40 ]
让我与你握别-再轻轻抽出我的手-知道思念从此生根...年华从此停顿-热泪在心中汇成河流-是那万般无奈的凝视...就把祝福别在襟上吧-而明日-明日又隔天涯
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