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[ Last edited by yinguojie on 2011-5-13 at 19:52 ]

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chemistry2228

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Recent studies showed that the product of  4 - cyanopyridine react with copper chloride was three-dimensional coordination polymer, while  the product of 4 - pyridine carboxylic acid react with copper chloride was only mononuclear complexes in the same hydrothermal conditions£¬ which  indicated that the hydrothermal reaction conditions, the slow hydrolysis of cyano is more conducive to the formation of  complex topology complexes.
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chemistry2228

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yinguojie(½ð±Ò+33, ·­ÒëEPI+1): ÐÁ¿àÁË£¬ÄãÃÇ·­ÒëµÄ¶¼²»´í£¬Ò»ÈËÒ»°ë°É£¬Ð»Ð»°¡~ 2011-05-13 22:46:39
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Recent studies showed that the product of  4 - cyanopyridine react with copper chloride was three-dimensional coordination polymer, while  the product of 4 - pyridine carboxylic acid react with copper chloride was only mononuclear complexes in the same hydrothermal conditions£¬ which  indicated that the slow hydrolysis of cyano is more conducive to the formation of  complex topology complexes  under the hydrothermal reaction conditions.
3Â¥2011-05-13 20:48:54
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yinjuanchen

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Originally posted by yinguojie at 2011-05-13 19:42:54:
²¢ÇÒÓÉÎÄÏ׿ÉÖª£¬µ±4-Çè»ùßÁऺÍ4-ßÁà¤ôÈËáÔÚÏàͬˮÈȺϳÉÌõ¼þÏÂÓëÂÈ»¯Í­·´Ó¦Ê±£¬Ç°Õߵõ½ÈýάÅäλ¾ÛºÏÎ¶øºóÕßÖ»µÃµ½Á˵¥ºËÅäºÏÎÕâ˵Ã÷ÔÚË®ÈÈ·´Ó¦Ìõ¼þÏ£¬Çè»ùµÄ»ºÂýË®½â¸üÓÐÀûÓÚÐγɸ´ÔÓÍØÆË½á¹¹µÄÅäºÏÎï¡£ ...

According to the literature, at the same hydrothermal synthesis condition, the reactions of  copper chloride with  4-Cyanopyridine and 4-pyridylcarboxsylic acid can produce three-dimensional coordination polymer and mononuclear complex, respectively. The result indicates that  slow hydrolysis of cyano-group is beneficial to synthesizing complex with complicated topological structures at hydrothermal reaction.
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4Â¥2011-05-13 20:50:13
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yinjuanchen

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yinguojie(½ð±Ò+33): ÐÁ¿àÁË£¬ÄãÃÇ·­ÒëµÄ¶¼²»´í£¬Ò»ÈËÒ»°ë°É£¬Ð»Ð»°¡~ 2011-05-13 22:46:50
Recent studies showed that the product of  4 - cyanopyridine reacted with copper chloride was three-dimensional coordination polymer, while  the product of 4 - pyridine carboxylic acid reacted with copper chloride was only mononuclear complexes at the same hydrothermal conditions£¬ which  indicated that the slow hydrolysis of cyano is more conducive to the formation of  complex topology complexes  under the hydrothermal reaction conditions.
ÎÒÌæÄã¸ÄÁËÒ»ÏÂreacted,µ«ÊÇÄãÕû¸ö¾ä×ÓÌ«³¤£¬Ç°Ò»¾äÖØ¸´Ì«¶àÏÔµÃÀÛ׸£¬ºóÃæµÄ¶¨Óï´Ó¾äµÄÏÈÐдÊÊÇʲô£¿Ö¸´ú½á¹ûµÄ£¬ÏÈÐдÊÌ«³¤£¬Ä¿Ç°Ã»¼ûµ½¹ýÕâÖÖÓ÷¨¡£¿ÉÒÔÓÃresult ½«¾ä×Ó¼ò¶Ì£¬²»Ê¹Óö¨Óï´Ó¾ä£¬ÕâÑù¼ò½àÒ×¶®¡£
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5Â¥2011-05-13 20:57:12
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yinjuanchen

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ÒýÓûØÌû:
Originally posted by chemistry2228 at 2011-05-13 20:48:54:
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Recent studies showed that the product of  4 - cyanopyridine react with copper chloride was three-dimensional coordination polymer, while  the product of 4 - pyridine carboxylic ...

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6Â¥2011-05-13 21:29:56
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