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| In conclusion, we propose a new route to obtain pyridines, pyrimidines and quinolines bearing a boronic acid group. Our original strategy was based on the formation of Grignard azine reagent and the particular reactivity of tris-trimethylsilylborate under mild conditions. Currently we are studying an extension to various substituted polyazines in view of their application to Suzuki cross-coupling reactions. |
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2楼2011-05-01 18:54:39