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lingling0302银虫 (小有名气)
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| Hydrothermal synthesis has afforded coordination polymers incorporating the kinked dipodal organodiimine 4,4′- dipyridylamine (dpa) and the flexible aliphatic dicarboxylate suberate dianion, with a general formulation of [M(sub)(dpa)(H2O)]n (sub ) suberate, M ) Co, 1; M ) Ni, 2). Both 1 and 2 exhibit crystallographically disordered suberate ligands, producing a threedimensional “ligand vacancy” R-Po coordination polymer network composed of two different types of [M(sub)(dpa)(H2O)]n idealized layers. |
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seaharrier
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2楼2011-04-21 13:56:01
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3楼2011-04-22 18:34:47
